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What do you understand by molar conductivity at infinite dilution

What do you understand by molar conductivity at infinite dilution

1 Answer

At infinite dilution, when dissociation is complete, each ion makes a definite contribution towards equivalent conductance of the electrolyte irrespective of the nature of the ion with which it Is associated and the value of equivalent conductance at infinite dilution for any electrolyte is the sum of contribution of its constituent ions", i.e., anions and cations. Thus,

$\lambda_eq^{\infty} = \lambda_c^{\infty} + \lambda_a^{\infty}$

$\lambda_eq^{\infty}$ - Equivalence Conductivity at Infinite Dilution

$\lambda_c^{\infty}$ - Conductivity of cation

$\lambda_b^{\infty}$ - Equivalence Conductivity of Anions
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