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Which one of the following reactions is not correct?

(1) $ CH_3CHO+ \large\frac{1}{2}O_2\: \:  \underrightarrow{Mn(OAc)/air}\: \:  CH_3COOH$

(2) $CH_3CH_2OH+O_2\: \: \underrightarrow {Micoderma\: aceti}\: \: CH_3COOH+H_2)$

(3) $ CH_3MgBr\: \:  \overset{\overset{(1)CO_2}{\longrightarrow}}{(2)H_3O^{\oplus}}\: \: CH_3COOH+ Mg(OH)Br$

(4) $CH_3OH+CO \:\: \underrightarrow{Ca/\Delta, pressure}\: \: CH_3COOH$

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