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The pair of chemicals that maintain heat balance in troposphere are

$\begin {array} {1 1} (1)\;CO_2,O_2^{\oplus} & \quad (2)\;N_2,O_2 \\ (3)\;O^{\oplus},O_3 & \quad (4)\;H_2O,NO^{\oplus} \end {array}$

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(2) $N_2,O_2$
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