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For thermal decomposition of ozone to oxygen:Step (i):$O_3\;\;\;\overset{\overset{k_1}{\rightleftharpoons}}{k_{-1}}\;\;\; O_2+O$.Step (ii):$O_3+O\;\;\;\underrightarrow{k_2}\;\;\;2O_2$ then rate will be $\{k_{-1}[O_2] > > k_2[O_3]\}$

$\begin{array}{1 1}(a)\;r=-k[O_3][O_2]\\(b)\;r=-k[O_3]/[O_2]\\(c)\;r=-k[O_3]^2/[O_2]\\(d)\;r=-k[O_3]^2[O_2]\end{array}$

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