$(a)\;1:1\qquad(b)\;1:2\qquad(c)\;2:1\qquad(d)\;1:3$

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$P'_{N_2} = P_T \times mole\;fraction\;of\;N_2$

$P'_{CO} = P_T \times mole\;fraction\;of\;CO$

$\large\frac{P'_{CO}}{P'_{N_2}} = \large\frac{mole\;fraction\;of\;N_2}{mole\;fraction\;of\;CO}$

$\;\;\;\;\;\;\;\;\;=\large\frac{moles\;of\;N_2}{moles\;of\;CO}$

$\;\;\;\;\;\;\;\;\;\;=\large\frac{\large\frac{w}{28}}{\large\frac{w}{28}}$

$\;\;\;\;\;\;\;\;\;\;=1:1$

Hence answer is (a)

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