$(a)\;\large\frac{6}{13}\;\large\frac{p_{0}V_{0}}{nR}\qquad(b)\;-\large\frac{6}{13}\;\large\frac{p_{0}V_{0}}{nR}\qquad(c)\;\large\frac{1}{13}\;\large\frac{p_{0}V_{0}}{nR}\qquad(d)\;-\large\frac{1}{13}\;\large\frac{p_{0}V_{0}}{nR}$