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The two isomers X and Y with the formula $Cr(H_2O)5CIBr_2$ were taken for experiment on depression in freezing point. It was found that one mole of X gave depression corresponding to 2 moles of particles and one mole of Y gave depression due to 3 moles of particles. The structural formulae of X and Y respectively are

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$Cr(H_2O)4Br_2]Cl.H_2O ; [Cr(H_2O)_5Cl]Br_2$
Hence (D) is the correct answer.
answered Jun 13, 2014