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Which of the following salts is not formed when $CuSO_4.5H_2O$ is heated ?

$\begin {array} {1 1} (A)\;CuSO_4.3H_2O & \quad (B)\;CuSO_4.2H_2O \\ (C)\;CuSO_4.H_2O & \quad (D)\;CuSO_4 \end {array}$

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