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Answers posted by meena.clay6
Questions
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Why on increasing pressure for real gases compressibility factor(Z) increas
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Nov 27, 2018
Solution : In statistical mechanics the description $Z= \large\frac{pV}{nRT}$Where $\rho$ is the pre...
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The enthalpy of sublimation of iodine is 62.8 kJ/mol. The bond dissociation
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Nov 27, 2018
Solution : $Cl -Cl (g) \to 2Cl(g) \delta H_1=242.3\;kj/mol$$I-I(g) \to 2l(g) \Delta H_2 =151.0$$\del...
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What can affect the magnitude of equilibrium constant Kp of a reversible gaseous reaction
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Nov 26, 2018
Solution : Change in concentration, pressure, catalyst, inert gas addition, etc. have NO effect on E...
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The relation between $K_c$ and $K_p$ is
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Nov 26, 2018
Solution : $Kp = Kc (RT) Delta n$where:Kp is the equilibrium constant in terms of pressure (pascals)...
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A basic Buffer solution can be prepared by mixing
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Nov 26, 2018
Solution :A mixture of weak base and its salt of strong acid in a water medium is called as a basic ...
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A large value of Kc means that at equilibrium
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Nov 26, 2018
Solution : If Kc is very large, ~1000 or more, we will have mostly product species present at equili...
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In an exothermic reversible reaction increase in temp shifts the equilibrium to
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Nov 26, 2018
Solution :For an exothermic reaction, heat is essentially a product of the reaction. In keeping with...
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A reaction is reversible because
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Nov 26, 2018
Solution : In reversible reactions, as the reactants react with other reactants to form products, th...
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Which of the following weakest ?
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Nov 26, 2018
Solution : Smaller the Kb value , weaker is the base
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$EDTA$ is a/an
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Nov 26, 2018
Solution : EDTA is Arrhensius acid it can given $H^+$ ions in aqueous solution , bronsted base, as i...
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With increase in temperature , ionic product of water .
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Nov 26, 2018
Solution : With increase in temperature ,ionic product increase, because self ionisaion of endotherm...
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One of the following is a bronsted acid hot not a bronsted base
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Nov 26, 2018
Solution : $H_2S$ can donate proton but can't accept protons
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Conjugate base of hydrazonic acid is :
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Nov 23, 2018
Solution :$N_3H \to N_3^{-}+H^{+}$Hydrozonic acid $=N_3H$
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Which of the following is a base according to lowry- bronsted concept?
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Nov 23, 2018
Solution :$I^{-}$ can accept protons and hence is a base
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The solubility product of $AgCl$ is $4 \times 10^{-18}$ at $298\;k$ . The solublity of AgCl in $0.04\;MCaCl_2$ will be
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Nov 23, 2018
Solution :$4 \times \large\frac{10^{-10}}{0.08}$$=[Ag^{+}]=5 \times 10^{-9}\;M$
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A certain buffer solution contains equal concentration of $X^{-}$ and $HX.K_4$ for $HX$ is $10^{-4}$. The $p^{H}$ of buffer is
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Nov 22, 2018
Solution :$p^{H}= pK_a+ \log \large\frac{[Salt]}{[Acid]}$$\qquad= \log K_a +\log 1$$\qquad= -\log 1...
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$P^{H}$ of $10^{-3}\;M$ solution of HCL in water is
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Nov 22, 2018
Solution :$[H^{+}]= 10^{-4}+10^{-7}=10^{-8}(1+10)=11 \times 10^{-9}\;M$$\qquad= -(1.0414 -8)$$\qquad...
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Equal volumes of two solution of $p^H3$ and 4 are mixed The $p^{H}$ of the resulting solution will be
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Nov 22, 2018
Solution :$p^{H}=3 $ means $[H^+]=10^{-3}\;M$$p^{H}$ means $[H^+]=10^{-4}\;M$$\qquad= \large\frac{0....
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Process by which ammonia is produced by reaction of nitrogen with hydrogen at 200 atm pressure and in presence of a catalyst is called
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Nov 19, 2018
Solution :The Haber process, also called the Haber–Bosch process, is an artificial nitrogen fixation
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Reactions in which reactants react to form products and simultaneously products reverse back in to reactants are called
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Nov 19, 2018
Solution :A reversible reaction is a chemical reaction where the reactants form products that, in tu...
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Rate at which a substance reacts is directly proportional to its
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Nov 19, 2018
Solution :The rate at which a substance reacts is directly proportional to its active mass and the r...
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Which of following is used as catalyst in contact process?
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Nov 19, 2018
Solution : The contact process is the current method of producing sulfuric acid in the high concentr...
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State at which forward and reverse reactions occur at same rate is
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Nov 19, 2018
Solution :A reaction that can take place in both the forward and reverse directions; leads to an equ...
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Equilibrium constant can be used to determine equilibrium concentration of equilibrium mixture knowing the
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Nov 19, 2018
Solution :Equilibrium constant can be used to determine equilibrium concentration of equilibrium mix...
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In reverse reaction $SO_3$ decomposes in to
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Nov 19, 2018
Solution :Sulfur trioxide decomposes to give sulfur dioxide and oxygen $2SO_3(g)$
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Due to high concentration of reactants, rate of forward reaction is
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Nov 19, 2018
Solution :If the concentration of a substance is changed, the equilibrium will shift to minimise the...
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Rate at which reaction proceeds is directly proportional to
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Nov 16, 2018
Solution :The rate at which the reaction proceeds is directly proportional to the product of the act...
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For the following reaction in gaseous phase $CO+\large\frac{1}{2}$$O_2 \rightleftharpoons CO_2$ and $\large\frac{K_c}{K_p}$ is
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Nov 16, 2018
Solution :$(b)\;(RT)^{-1/2}$
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$P^H$ of $0.1\;M$ Solution of weak acid is 3. The value of ionisation constant $Ka$ of acid is
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Nov 16, 2018
Solution :$P^H$ of $0.1\;M$ Solution of weak acid is 3. The value of ionisation constant $Ka$ of aci...
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The $p^{Ka}$ of a weak acid $HA$ is $4.80$ The $pK_b$ of a weak base BOH is $4.78$ .The $p^{H}$ of an aqueous solution of the corrosponding salt $BA$ will be
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Nov 16, 2018
Solution :For Salt of weak acid and weak base ,$p^{H}= \large\frac{1}{2}$$[ \log Ka+\log kw - \log K...
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Species acting both as bronsted acid and a base is
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Nov 16, 2018
Solution :$HSO_4$ can act as a bronsted acid as well as bronsted base.
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Ammonium ion is
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Nov 16, 2018
Solution :Ammonium ion $(NH_4^+)$ is a conjugate acid $NH_3$$NH_3+H_2O \rightleftharpoons NH_4^++OH^...
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Water is a
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Nov 16, 2018
Solution :Water is an amphiprotic solvent as it can accepted protons as well as give protons
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For the reaction $2NO_{(2g)} \rightleftharpoons 2NO_{(g)}+O_{2(g)} \qquad K_c=1.8 \times 10^{-6}$ at $184^{\circ} c R=0.0831\;KJ/mol\;K$ When $K_p$ and $K_c$ are compared at $184^{\circ}$ it is found that :
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Nov 15, 2018
Solution :$KP=K_c (RT)^{\Delta n (g)}$$\Delta n(g)=1$$\qquad= Kc \times 0.0831 \times 457$It means $...
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Three reaction involving $H_2PO_4$ are given below $(i)H_3PO_4+H_2O \rightleftharpoons H_3O^{+}+H_2PO_4^{-} \\ (ii)H_2PO_4+H_2O \rightleftharpoons HPO_{4}^{-2}+H_3^{+}O \\ (iii)H_2PO_4+OH \rightleftharpoons H_3PO_4+O^{2-}$ In which of the above does $H_2PO_4$ act as an acid
answered
Nov 15, 2018
Solution :According to lowry bronsted acid base theory in (ii) reaction $H_2PO_4$ donates $H^{+}$ion...
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A vessel contains $CO_2$ at $1000\;K$ temperature with pressure $0.5$ atm. Some of $CO_2$ is converted in to CO on addition of graphite . If total pressure at equilibrium is $0.8$ atm the value of $K_p$ is
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Nov 15, 2018
Solution :$CO_{2(g)}+C_{(g)} \rightleftharpoons 2CO_(g)$initial pressure 0.5 atm 0final pressure $=0...
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The following equilibrium constant are given : $N_2+3H_2 \rightleftharpoons 2NH_3;K_1 \\ N_2+O_2 \rightleftharpoons 2NO;K_2\\H_2+1/2O_2 \rightleftharpoons +H_2OK_3 $ The equilibrium constants for the oxidation of $NH_3$ by oxygen to given NO is :
answered
Nov 14, 2018
Solution :The required equation for the oxidation of $NH_3$ by oxygen given No$(a)\;K_2K_3^3/K_1 $
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Calculate the pH of the solution when $0.1\; M\; CH_3 COOH (50 ml)$ and $0.1\; M\; NaOH (50 ml)$ are mixed, $[Ka (CH_3COOH)=10^{-5}]$
answered
Nov 13, 2018
Solution :$CH_3COOH \to CH_3COO_{-}+H^{+}$..........(I)$NaOH \to Na^{+}+OH^{-}$$H^{+}+OH_{-} \to H_2...
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Equilibrium constant changes with
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Nov 13, 2018
Solution :A temperature change occurs when temperature is increased or decreased by the flow of heat...
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Equilibriam are those in which the reactants and products are present in more than phases:
answered
Nov 13, 2018
Solution :A system whose reactants, products, or both are in more than one phase is a heterogeneous ...
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