Which one of the following pairs of solution is not an acidic buffer ?

Question

( A ) $H_3PO_4$ and $Na_3PO_4$
( B ) $H_2CO_3$ and $Na_2CO_3$
( C ) $CH_3COOH$ and $CH_3COONa$
( D ) $HClO_4$ and $NaClO_4$