In the electrochemical cell - <br> $Zn|ZnSO_4 \; (0.01 M) || CuSO_4 \; (1.0 M) | Cu$, the emf of this Daniel cell is $E_1$. When the concentration of $ZnSO_4$ is changed to $0.1 M$ and that of $CuSO_4$ changed to $0.01 M$, the emf changes to $E_2$. From the followings, which one is the relayionship between $E_1$ and $E_2$ ? (Given , $\frac{RT}{F} = 0.059$)