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JEEMAIN-2014
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Q)
Amount of oxalic and present in a solution can be determined by its nitration with
k
M
n
O
4
solution in the presence of
H
2
S
O
4
. The nitration gives unsatisfactory result when carried out in the presence of Hcl because Hcl
reduces permanganate to
M
n
2
+
Oxidises oxalic acid to carbon dioxide and water
gets oxidized by oxalic acid to chlorine
furnishes
H
+
ions in addition to those from oxalic acid
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