Assuming that water vapour is an ideal gas, the internal energy change (ΔU) when 1 mole of water is vapourised at 1 bar pressure and 100∘C, (Given : molar enthalpy of vaporisation of water at 1 bar and 373 K = 41 kJ mol−1 and R = 8.3 J mol−1 K−1 ) will be :