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Select the incorrect statement :- (1) Stoichiometry of crystal remains unaf

Select the incorrect statement :- (1) Stoichiometry of crystal remains unaffected due to schottky defect (2) Frenkel defect is usually shown by ionic compounds having low co-ordination number (3) F-centres generation is responsible factor for imparting the colour to the crystal (4) Density of crystal always increases by doping
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