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An electronic transition in hydrogen atom results, in the formation of $H_{\alpha}$ line of hydrogen in Lyman series, the energies associated with the electron in each of the orbits involved in the transition (in $kCal mol^{-1}$) are

\[\begin {array} {1 1} (1)\;-313.6,-34.84 & \quad (2)\;-313.6, -78.4 \\ (3)\;-78.4,-34.84 & \quad (4)\;-78.4,-19.6 \end {array}\]

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