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The rate law for decomposition of N2O5:N2O52NO2+12O2 is consistent with observed rate law.If k=5×104s1 the time required for [N2O5] be reduced to 10% of its original value.

N2O5kNO2+NO3(fast)

NO2+NO3k1NO2+NO+O2(slow)

NO+NO3k22NO2(fast)

'K' is rate constant of reaction: N2O52NO2+12O2

(a)5.2×103s(b)4.9×103(c)4.6×103s(d)6.1×103s

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