Which one of the following has an optical isomer

Question

$\begin{array}{1 1}(a)\;[Zn(en)(NH_3)_2]^{2-}&(b)\;[CO(en)_3]^{3+}\\(c)\;[CO(H_2O)_4(en)]^{3+}&(d)\;[Zn(en)_2]^{2+}\end{array}$