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JEEMAIN and NEET
>>
Chemistry
>>
Electrochemistry
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Q)
Given the overall formation constant of the
[
F
e
(
C
N
)
6
]
−
4
ion as
10
35
and the standard potential for half reaction
F
e
+
3
+
e
−
⇋
F
e
+
2
,
E
0
=
0.77
V
,
[
F
e
(
C
N
)
6
]
−
3
+
e
−
⇋
[
F
e
(
C
N
)
6
]
−
4
,
E
0
=
0.36
V
.Then the overall formation constant of
[
F
e
(
C
N
)
6
]
−
3
ion is
(
a
)
8
×
10
92
(
b
)
6.3
×
10
14
(
c
)
8.59
×
10
41
(
d
)
9
×
10
36
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