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Which of the following reactions is used to estimate Copper volumetrically ?

(a)2Cu2++4ICu2I2+I2(b)2Cu2++2CNS+SO2+2H2OCu2(CNS)2+H2SO4+2H+(c)2Cu2++4CNCu2(CN)2+(CN)2(d)Cu2++4NH3[Cu(NH3)4]2+
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