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Which among the following statements are correct with respect to adsorption of gases on a solid?


1. The extent of adsorption is equal to kpn according to Freundlich isotherm.
2. The extent of adsorption is equal to kp1/n according to Freundlich isotherm.
3. The extent of adsorption is equal to a+bpap according to Langmuir isotherm.
4. The extent of adsorption is equal to ap1+bp according to Langmuir isotherm.
5. Freundlich adsorption fails at a low pressure.

(a) 1 and 3
(b) 1 and 4
(c) 2 and 3
(d) 2 and 4
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