The reactions given below , are the catalyst and corresponding process / reaction are matched , the mismatch is

Question

$(a)\;[RhCl\;(pph_{3})_{2}]\;:hydrogenation\qquad(b)\;Ticl_{4}+Al(C_{2}H_{5})_{3} \;: polymerization\qquad(c)\;N_{2}O_{5}\;:Haber\;Bosch\;process\qquad(d)\;nickel\;:hydrogenation$