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Which of the following equations is not actually observed?

4Sn+10HNO3(dilute)4Sn(NO3)2+NH4NO3+3H2O3Sn+8HNO3(dilute)3Sn(NO3)2+2NO+4H2OSn+2HCl(conc)SnCl2+H2Sn+2H2SO4(conc)SnSO4+2H2O+SO2

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