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Which of the following is not an example of Disproportionation in acidic medium?

(1)2Mn3++2H2OMn2++MnO2+4H+ (2)3MnO24+2H2OMnO2+2MnO4+4OH (3)3MnO24+4H+2MnO4+MnO2+2H2O (4)2MnO4+3Mn2++2H2O5MnO2+4M
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