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JEEMAIN-2014
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Q)
The formation of the oxide ion
0
2
−
(
g
)
requires first on exothermic and then an endothermic step.
O
(
g
)
+
e
−
→
O
−
(
g
)
;
Δ
r
∘
=
−
142
k
j
m
o
l
−
1
O
(
g
)
+
e
−
→
O
2
−
(
g
)
;
Δ
r
∘
=
+
844
k
j
m
o
l
−
1
This is because of
Oxygen is more electropositive
Oxygen has high electron affinity
O
−
ion will tend to resist the addition of another electron
O
−
ion has comparability larger size than oxygen atom.
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