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The formation of the oxide ion 02(g) requires first on exothermic and then an endothermic step. O(g)+eO(g);Δr=142kjmol1O(g)+eO2(g);Δr=+844kjmol1This is because of

Oxygen is more electropositiveOxygen has high electron affinityO ion will tend to resist the addition of another electronO ion has comparability larger size than oxygen atom.
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