Let $\overrightarrow{a}, \overrightarrow{b}$ and $\overrightarrow{c}$be three unit vectors such that
$\overrightarrow{a} \times (\overrightarrow{b} \times \overrightarrow{c}) = \large\frac{3}{2}(\overrightarrow{b}+\overrightarrow{c})$. If $\overrightarrow{b}$ If
$\overrightarrow{b}$ is not parallel to $\overrightarrow{c}$ ,
then the angle between
$\overrightarrow{a}$ and $\overrightarrow{b}$ is :