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Sodium extract is heated with concentrated HNO3 before testing for halogens because :

(1) Silver halides are totally insoluble in nitric acid.(2) Ag2 and AgCN are soluble in acidic medium.(3) S2 and CN, if present, are decomposed by conc.HNO3 and hence do not interfere in the test.(4) Ag reacts faster with halides in acidic medium.

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