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Sodium salt of an organic acid ‘X’ produces effervescence with conc. H2SO4. ‘X’ reacts with the acidified aqueous CaCl2 solution to give a white precipitate which decolourises acidic solution of KMnO4 ‘X’ is :

(1)CH3COONa(2)Na2C2O4(3)C6H5COONa(4)HCOONa

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