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Recent questions in Chemical Thermodynamics
Questions
>>
JEEMAIN and NEET
>>
Chemistry
>>
Chemical Thermodynamics
How to solve this question
asked
Jan 20, 2017
by
1999guptaamit
1
answer
For the vaporization process of HI, the molar entropy and molar enthalpy are respectively,
89.0
J
K
−
1
m
o
l
−
1
and
21.16
k
J
m
o
l
−
1
. The temperature at which the value of
Δ
G
becomes zero for this process is:
jeemain
chemistry
chemical-thermodynamics
asked
Jan 18, 2016
by
meena.p
1
answer
why ΔH = energy used in bond breaking reactions − energy released in bond making products and not ΔH = energy released in bond making products - energy used in bond breaking reactions .
chemistry
asked
Jan 20, 2015
by
venkatesh.purushotham
1
answer
A
75.0
g
sample of a metal is heated by adding
450
J
of heat. If it's temperature increases from
22
∘
C
to
37
∘
C
, what is the molar mass of the metal?
jeemain
chemistry
chemical-thermodynamics
medium
asked
Mar 22, 2014
by
balaji.thirumalai
1
answer
In exothermic reaction
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
easy
asked
Mar 14, 2014
by
meena.p
1
answer
Bomb calorimeter used for determining change in internal energy at constant _____
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
easy
asked
Mar 14, 2014
by
meena.p
1
answer
Which of the following statement is false
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
easy
asked
Mar 14, 2014
by
meena.p
1
answer
For spontaneous reaction
Δ
G
is
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
easy
asked
Mar 14, 2014
by
meena.p
1
answer
During fusion, the entropy of the system
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
easy
asked
Mar 14, 2014
by
meena.p
1
answer
At constant temperature and pressure which one of the following statements is correct for the reaction?
C
O
(
g
)
+
1
2
O
2
(
g
)
⟶
C
O
2
(
g
)
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
easy
asked
Mar 14, 2014
by
meena.p
1
answer
In a reversible adiabatic change
Δ
S
is
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
easy
asked
Mar 14, 2014
by
meena.p
1
answer
In which of the following process does the entropy decrease?
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
medium
asked
Mar 14, 2014
by
meena.p
1
answer
Heat of neutralization of a strong acid and weak base is
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
medium
asked
Mar 14, 2014
by
meena.p
1
answer
In an exothermic reaction , heat is
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
medium
asked
Mar 14, 2014
by
meena.p
1
answer
When a gas at high pressure expands into a region of low pressure , then its temperature
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
medium
asked
Mar 14, 2014
by
meena.p
1
answer
Two moles of an ideal gas expand spontaneously into a vaccum. The work done is
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
medium
asked
Mar 13, 2014
by
meena.p
1
answer
The Joule-Thomson expansion of an ideal gas is an
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
medium
asked
Mar 13, 2014
by
meena.p
1
answer
In isothermal change which of the following parameter is constant
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
medium
asked
Mar 13, 2014
by
meena.p
1
answer
A system which can change neither matter nor energy with the surroundings is called
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
medium
asked
Mar 13, 2014
by
meena.p
1
answer
Calculate the enthalpy change when
50
m
l
of
0.01
M
C
a
(
O
H
)
2
reacts with
25
m
l
of
0.01
M
H
C
l
.
Given that
Δ
H
0
n
e
u
t
of a strong acid and strong base is
140
cal/ equivalent
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
The heat of neutralization is highest in
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
For the reaction :
C
7
H
8
(
I
)
+
9
O
2
(
g
)
⟶
7
C
O
2
(
g
)
+
4
H
2
O
(
I
)
, the calculated heat of reaction is
232
k
J
/
m
o
l
and observed heat of reaction is
50.4
k
J
/
m
o
l
,
then the resonance energy is
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
A system is taken from state A to state B along two different paths 1 and 2. The Work done on the system along these two path is
W
1
and
W
2
The heat absorbed by the system along these paths are
Q
1
and
Q
2
respectively. Then
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
The process in which heat is neither allowed to enter nor allowed to leave the system but in which temperature changes in known as
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
Inversion Temperature is
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
Which is equal to the total work done?
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
For an ideal gas
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
100
m
L
of
0.10
M
H
C
l
is mixed with
100
m
L
of
0.10
M
N
a
O
H
.
The solution temperature rises by
6.0
∘
C
.
Calculate the enthalpy of neutralization per mole of
H
C
l
.
sat
chemistry
chemical-
reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
An ideal Carnot heat engine operates on a temperature difference of
210
degrees. One third of the heat absorbed from the source is discharged to the sink. If the work done per cycle is
400
J
. The amount of heat released
(
q
1
)
at the sink is
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
An ideal Carnot heat engine operates on a temperature difference of
210
degrees. One third of the heat absorbed from the source is discharged to the sink. If the work done per cycle is
400
J
.
The amount of heat absorbed
(
q
2
)
by an engine at source is _________
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
An ideal Carnot heat engine operates on a temperature difference of
210
degrees. One third of the heat absorbed from the source is discharged to the sink. If the work done per cycle is
400
J
. Efficiency
(
η
)
of an ideal carnot heat engine is
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
An ideal Carnot heat engine operates on a temperature difference of
210
degrees. One third of the heat absorbed from the source is discharged to the sink. If the work done per cycle is
400
J
.
Sink
(
T
1
)
and Source
(
T
2
)
temperatures respectively are
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
In an open beaker held at
27
∘
C
and
1
a
t
m
pressure containing dilute sulphuric acid,
100
g
zinc were added. The work done by the liberated gas is _______
jeemain
cbse
chemistry
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
For which of the following change
Δ
H
=
Δ
E
?
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
cbse
chemical-thermodynamics
class11
unit6
difficult
asked
Mar 13, 2014
by
meena.p
1
answer
The enthalpy of sublimation of iodine is 62.8 kJ/mol. The bond dissociation energies for
C
l
2
,
I
2
and ICl are 242.3, 151.0 and 211.3 kJ/mol, respectively. The standard enthalpy of formation of ICl(g) is nearly equal to
jeemain
chemistry
class11
unit6
chemical-thermodynamics
difficult
asked
Mar 1, 2014
by
mosymeow_1
1
answer
The following equation shows the conversion of limes stone to lime
C
a
C
O
3
(
s
)
⟶
C
a
O
(
s
)
+
C
O
2
(
g
)
. The values of
Δ
H
∘
and
Δ
S
∘
are
+
179.1
k
J
and
160.2
J
/
K
respectively at
298
K
and
1
b
a
r
. Assuming that
Δ
H
∘
and
Δ
S
∘
do not change with temperature, minimum temperature above which conversion of lime stone to lime will be spontaneous is
jeemain
chemistry
class11
unit6
chemical-thermodynamics
medium
mock
asked
Feb 28, 2014
by
mosymeow_1
1
answer
Conversion of A to B is carried out by the following process:
Δ
S
(
A
→
C
)
=
50
e
V
,
Δ
S
(
C
→
B
)
=
30
e
V
,
Δ
S
(
B
→
D
)
=
20
e
V
, where eV, where eV, is entropy unit, then
Δ
S
(
A
→
B
)
is
jeemain
chemistry
class11
unit6
chemical-thermodynamics
medium
asked
Feb 28, 2014
by
mosymeow_1
1
answer
The enthalpy of hydrogenation of cyclohexene is -119.5 kj/mol. What is the enthalpy of benzene, if its resonance energy is -150.4 kJ/mol?
jeemain
chemistry
class11
unit6
chemical-thermodynamics
difficult
asked
Feb 28, 2014
by
mosymeow_1
1
answer
For the formation of carbon monoxide (CO) from the elements at 298 K
(
Δ
H
−
Δ
U
)
is (R=8.314
J
K
−
1
m
o
l
−
1
)
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
class11
unit6
chemical-thermodynamics
medium
asked
Feb 28, 2014
by
mosymeow_1
1
answer
Given, standard enthalpy of formation
(
Δ
f
H
∘
)
at 298 k for methane is -74.8 kJ/mol. What other information is required to determine the average energy for C-H bond formation would be
jeemain
chemistry
class11
unit6
chemical-thermodynamics
medium
asked
Feb 28, 2014
by
mosymeow_1
1
answer
One mole of monoatomic ideal gas at T (K) is expanded from 1 L to 2 L adiabitcally under constant external pressure of 1 atm. The final temperature of gas in kelvin is
jeemain
chemistry
class11
unit6
chemical-thermodynamics
difficult
asked
Feb 28, 2014
by
mosymeow_1
1
answer
The enthalpy of vaporisation of a liquid is 30 kJ/mol and entropy of vaporisation is 75
J
m
o
l
−
1
K
−
1
. What is the boiling point of the liquid at 1 atm?
jeemain
chemistry
class11
unit6
chemical-thermodynamics
difficult
asked
Feb 28, 2014
by
mosymeow_1
1
answer
Which of the following reactions will define
Δ
H
∘
f
?
jeemain
chemistry
class11
unit6
chemical-thermodynamics
medium
asked
Feb 28, 2014
by
mosymeow_1
1
answer
The enthalpy of combustion of cyclohexane, cyclohexene and
H
2
are respectively -3920, -3800 and -241 kJ/mol. The heat of hydrogenation of cyclohexane is
jeemain
chemistry
class11
unit6
chemical-thermodynamics
difficult
asked
Feb 28, 2014
by
mosymeow_1
1
answer
Given a mole of a non-ideal gas which undergoes a change of state (2.0 atm, 3.0 L 95 K)
→
(4.0 atm, 5.0 L, 245 K) with a change in internalenergy,
Δ
U
= 30.0 L atm. What will be the change in enthalpy (
Δ
H
) of the process in L atm?
jeemain
chemistry
class11
unit6
chemical-thermodynamics
medium
asked
Feb 28, 2014
by
mosymeow_1
1
answer
At
27
∘
C
the enthalpy change for the transition of liquid water to steam is 30 kJ/mol. What would be the entropy change for the process?
jeemain
chemistry
class11
unit6
chemical-thermodynamics
easy
asked
Feb 28, 2014
by
mosymeow_1
1
answer
Which of the following gas has the highest heat of combustion?
sat
chemistry
chemical-reactions-and-thermochemistry
jeemain
class11
unit6
chemical-thermodynamics
easy
asked
Feb 28, 2014
by
mosymeow_1
1
answer
In a flask colourless
N
2
O
4
is in equilibrium with brown coloured
N
O
2
. At equilibrium when the flask is heated at
100
∘
C
, the brown colour deepens and on cooling it becomes less coloured. The changed in enthalpy,
Δ
H
for this system is
jeemain
chemistry
class11
unit6
chemical-thermodynamics
easy
asked
Feb 28, 2014
by
mosymeow_1
1
answer
For the decomposition of
A
g
2
O
at 298 K.
A
g
2
O
(
s
)
⟶
2
A
g
(
s
)
+
1
2
O
2
(
g
)
Δ
G
∘
= 11.21 kJ which of the following statement is true?
jeemain
chemistry
class11
unit6
thermodynamics
medium
asked
Feb 28, 2014
by
mosymeow_1
1
answer
If
Δ
H
∘
f
and
Δ
G
∘
f
of
C
H
3
O
H
(
g
)
at 298 K is -200.7 kJ/mol and -162 kJ/mol respectively, then absolute entropy of
C
H
3
O
H
(
g
)
at 298 K is (given absolute entropies of C(s),
H
2
(
g
)
and
O
2
(
g
)
at 298 K are 5.7, 130.60 and 205.00 J/mol respectively).
jeemain
chemistry
class11
unit6
chemical-thermodynamics
difficult
asked
Feb 28, 2014
by
mosymeow_1
1
answer
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