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JEEMAIN and NEET
>>
Chemistry
>>
Electrochemistry
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Q)
The voltage of cell given is -0.46V
P
t
/
H
2
(atm)/
N
a
H
S
O
3
(
0.4
M
)
,
N
a
2
S
O
3
(
6.44
×
10
−
3
M
)
∥
Z
n
+
2
(
0.3
M
)
/
Z
n
(
g
)
.Also
Z
n
+
2
+
2
e
−
→
Z
n
(
s
)
⇋
E
0
=
−
0.763
V.Then the value of
K
2
=
[
H
+
]
[
S
O
−
2
3
]
[
H
S
O
−
3
]
(
a
)
7.2
×
10
−
8
(
b
)
1.2
×
10
−
5
(
c
)
6.4
×
10
−
6
(
d
)
3.6
×
10
−
6
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