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CBSE XII
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Chemistry
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To $500cm^3$ of water $3.0\times 10^{-3}$kg of acetic acid is added .If 2.3% of acetic acid is dissociated.What will be the depression of freezing point?$K_f$ and density of water are $1.86$K kg/mol and $0.997g/cm^3$ respectively.
cbse
class12
chemistry
ch2
solutions
sec-c
medium
additionalproblem
q12
asked
Aug 6, 2014
by
sreemathi.v
1
answer
The freezing point of a solution containing 0.2g of acetic acid in 20.0g benzene is lowered by $0.45^{\large\circ}$C.Calculate the degree of association of acetic acid in benzene.Assume acetic acid dimerises in benzene.$K_f$ for benzene =$5.12Kmol^{-1}Kg$
cbse
class12
chemistry
ch2
solutions
sec-b
medium
additionalproblem
q11
asked
Aug 6, 2014
by
sreemathi.v
1
answer
If boiling point of an aqueous solution is 100.1$^{\large\circ}C$,what is its freezing point.Given,latent heat of fusion and vaporization of water as $80cal g^{-1}$ and $540cal g^{-1}$ respectively.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
additionalproblem
q10
asked
Aug 6, 2014
by
sreemathi.v
1
answer
A very small amount of a non-volatile solute (that does not dissociate) is dissolved in $56.8cm^3$ of benzene (density $=0.889gcm^{-3}$).At room temperature vapour pressure of this solution is 98.88mm Hg while that of benzene is 100 mm Hg.Find the molality of this solution.If the freezing temperature of this solution is 0.73 degree lower than that of benzene .What is the value of $K_f$ for benzene?
cbse
class12
chemistry
ch2
solutions
sec-b
medium
additionalproblem
q9
asked
Aug 6, 2014
by
sreemathi.v
1
answer
Find the molality of a solution containing a non-volatile solute if the vapour pressure is 2% below the vapour pressure of pure water.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
additionalproblem
q8
asked
Aug 6, 2014
by
sreemathi.v
1
answer
A 5% solution (wt/volume) of cane sugar is isotonic with 0.877% (wt/volume) of urea solution.Find the molecular weight of urea,if molecular weight of sugar is 342.
cbse
class12
chemistry
ch2
solutions
sec-b
easy
additionalproblem
q7
asked
Aug 6, 2014
by
sreemathi.v
1
answer
The Henry's law constant for oxygen dissolved in water is $4.34\times 10^4$ atm at $25^{\large\circ}$C.If the partial pressure of oxygen in air is 0.2atm,under atmospheric conditions,calculate the concentration (in moles per litre) of dissolve oxygen in water in equilibrium with air at $25^{\large\circ}$C.
cbse
class12
chemistry
ch2
solutions
sec-c
easy
additionalproblem
q6
asked
Aug 6, 2014
by
sreemathi.v
1
answer
The solubility of oxygen in water is $2.43\times 10^{-3}$ mole/litre at $25^{\large\circ}$C and 1.0atm pressure.Calculate the concentration of oxygen at $25^{\large\circ}$C and 0.2atm pressure.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
additionalproblem
q5
asked
Aug 6, 2014
by
sreemathi.v
1
answer
Calculate the molarity of water if its density is $1000g/m^3$
cbse
class12
chemistry
ch2
solutions
sec-a
easy
additionalproblem
q4
asked
Aug 6, 2014
by
sreemathi.v
1
answer
A sample of sulphuric acid is 98% $H_2SO_4$ by weight (density =$1.10gmL^{-1})$.Calculate normality
cbse
class12
chemistry
ch2
solutions
sec-b
medium
additionalproblem
q3-ii
asked
Aug 6, 2014
by
sreemathi.v
1
answer
A sample of sulphuric acid is 98% $H_2SO_4$ by weight (density =$1.10gmL^{-1})$.Calculate Molarity
cbse
class12
chemistry
ch2
solutions
sec-b
medium
additionalproblem
q3-i
asked
Aug 6, 2014
by
sreemathi.v
1
answer
1.8g of glucose (molar mass =180) are dissolved in 60g of water.Calculate the mole fraction of glucose and water
cbse
class12
chemistry
ch2
solutions
sec-a
easy
additionalproblem
q2-b
asked
Aug 6, 2014
by
sreemathi.v
1
answer
1.8g of glucose (molar mass =180) are dissolved in 60g of water.Calculate the molality
cbse
class12
chemistry
ch2
solutions
sec-a
easy
additionalproblem
q2-a
asked
Aug 6, 2014
by
sreemathi.v
1
answer
1.23g of sodium hydroxide (molar mass =40) are dissolved in water and the solution is made to $100cm^3$.Calculate the molarity of solution.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
additionalproblem
q1
asked
Aug 6, 2014
by
sreemathi.v
1
answer
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of $K_2SO_4$ in 2 litre of water at 25$^{\large\circ}$ C, assuming that it is completely dissociated.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.41
asked
Aug 6, 2014
by
sreemathi.v
1
answer
Determine the amount of $CaCl_2$ (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27$^{\large\circ}$ C.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.40
asked
Aug 6, 2014
by
sreemathi.v
1
answer
The air is a mixture of a number of gases. The major components are oxygen and nitrogen with approximate proportion of 20% is to 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 K if the Henry’s law constants for oxygen and nitrogen at 298 K are $3.30 \times 10^7$ mm and $6.51 \times 10^7$ mm respectively, calculate the composition of these gases in water.
cbse
class12
chemistry
ch2
solutions
sec-c
easy
bookproblem
q2.39
asked
Aug 6, 2014
by
sreemathi.v
1
answer
Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of toluene.
cbse
class12
chemistry
ch2
solutions
sec-c
medium
bookproblem
q2.38
asked
Aug 6, 2014
by
sreemathi.v
1
answer
Vapour pressures of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot $p_{total}, p_{chloroform}$, and $p_{acetone}$ as a function of $x_{acetone}$. The experimental data observed for different compositions of mixture is:
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.37
asked
Aug 6, 2014
by
sreemathi.v
1
answer
100 g of liquid A (molar mass $140 g mol^{–1}$) was dissolved in 1000 g of liquid B (molar mass $180 g mol^{–1}$). The vapour pressure of pure liquid B was found to be 500 torr. Calculate the vapour pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure of the solution is 475 torr.
cbse
class12
chemistry
ch2
solutions
sec-c
medium
bookproblem
q2.36
asked
Aug 6, 2014
by
sreemathi.v
1
answer
Henry’s law constant for the molality of methane in benzene at 298 K is $4.27 \times 10^5$ mm Hg. Calculate the solubility of methane in benzene at 298 K under 760 mm Hg.
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.35
asked
Aug 6, 2014
by
sreemathi.v
1
answer
Vapour pressure of water at 293 K is 17.535 mm Hg. Calculate the vapour pressure of water at 293 K when 25 g of glucose is dissolved in 450 g of water.
cbse
class12
chemistry
ch2
solutions
sec-c
easy
bookproblem
q2.34
asked
Aug 5, 2014
by
sreemathi.v
1
answer
19.5 g of $CH_2FCOOH$ is dissolved in 500 g of water. The depression in the freezing point of water observed is 1.00$^{\large\circ}$ C. Calculate the van’t Hoff factor and dissociation constant of fluoroacetic acid.
cbse
class12
chemistry
ch2
solutions
sec-c
medium
bookproblem
q2.33
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Calculate the depression in the freezing point of water when 10 g of $CH_3CH_2CHClCOOH$ is added to 250 g of water. $K_a = 1.4 \times 10^{–3}, K_f = 1.86 K kg mol^{–1}$.
cbse
class12
chemistry
ch2
solutions
sec-c
easy
bookproblem
q2.32
asked
Aug 5, 2014
by
sreemathi.v
1
answer
The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.
cbse
class12
chemistry
ch2
solutions
sec-b
easy
bookproblem
q2.31
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Calculate the amount of benzoic acid $(C_6H_5COOH)$ required for preparing 250 mL of 0.15 M solution in methanol.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.30
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Nalorphene $(C_{19}H_{21}NO_3)$, similar to morphine, is used to combat withdrawal symptoms in narcotic users. Dose of nalorphene generally given is 1.5 mg. Calculate the mass of $1.5 \times 10^{–3} m$ aqueous solution required for the above dose.
cbse
class12
chemistry
ch2
solutions
sec-c
medium
bookproblem
q2.29
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Calculate the mass percentage of aspirin ($C_9H_8O_4$) in acetonitrile ($CH_3CN$) when 6.5 g of $C_9H_8O_4$ is dissolved in 450 g of $CH_3CN$.
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.28
asked
Aug 5, 2014
by
sreemathi.v
1
answer
If the solubility product of CuS is $6 \times 10^{–16}$, calculate the maximum molarity of CuS in aqueous solution.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.27
asked
Aug 5, 2014
by
sreemathi.v
1
answer
If the density of some lake water is $1.25g mL^{–1}$ and contains 92 g of $Na^+$ ions per kg of water, calculate the molality of $Na^+$ ions in the lake.
cbse
class12
chemistry
ch2
solutions
sec-a
medium
bookproblem
q2.26
asked
Aug 5, 2014
by
sreemathi.v
1
answer
In the following compound, identify is it insoluble, partially soluble and highly soluble in water? Pentanol.
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.25-vi
asked
Aug 5, 2014
by
sreemathi.v
1
answer
In the following compound, identify is it insoluble, partially soluble and highly soluble in water? $CHCl_3$
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.25-v
asked
Aug 5, 2014
by
sreemathi.v
1
answer
In the following compound, identify is it insoluble, partially soluble and highly soluble in water? Ethylene glycol
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.25-iv
asked
Aug 5, 2014
by
sreemathi.v
1
answer
In the following compound, identify is it insoluble, partially soluble and highly soluble in water? Formic acid
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.25-iii
asked
Aug 5, 2014
by
sreemathi.v
1
answer
In the following compound, identify is it insoluble, partially soluble and highly soluble in water? Toluene
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.25-ii
asked
Aug 5, 2014
by
sreemathi.v
1
answer
In the following compound, identify is it insoluble, partially soluble and highly soluble in water? Phenol
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.25-i
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain. Cyclohexane, KCl, $CH_3OH, CH_3CN$.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.24
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Suggest the most important type of intermolecular attractive interaction in the following pair : acetonitrile ($CH_3CN$) and acetone ($C_3H_6O$).
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.23-v
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Suggest the most important type of intermolecular attractive interaction in the following pair : methanol and acetone
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.23-iv
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Suggest the most important type of intermolecular attractive interaction in the following pair : $NaClO_4$ and water
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.23-iii
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Suggest the most important type of intermolecular attractive interaction in the following pair : $I_2$ and $CCl_4$
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.23-ii
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Suggest the most important type of intermolecular attractive interaction in the following pair : n-hexane and n-octane
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.23-i
asked
Aug 5, 2014
by
sreemathi.v
1
answer
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
cbse
class12
chemistry
ch2
solutions
sec-a
medium
bookproblem
q2.22
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Two elements A and B form compounds having formula $AB_2$ and $AB_4$. When dissolved in 20 g of benzene ($C_6H_6$), 1 g of $AB_2$ lowers the freezing point by 2.3 K whereas 1.0 g of $AB_4$ lowers it by 1.3 K. The molar depression constant for benzene is 5.1 K $kg mol^{–1}$. Calculate atomic masses of A and B.
cbse
class12
chemistry
ch2
solutions
sec-c
medium
bookproblem
q2.21
asked
Aug 5, 2014
by
sreemathi.v
1
answer
A 5% solution (by mass) of cane sugar in water has freezing point of 271K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.20
asked
Aug 5, 2014
by
sreemathi.v
1
answer
A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate: vapour pressure of water at 298 K.
cbse
class12
chemistry
ch2
solutions
sec-c
difficult
bookproblem
q2.19-ii
asked
Aug 5, 2014
by
sreemathi.v
1
answer
A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate: molar mass of the solute
cbse
class12
chemistry
ch2
solutions
sec-c
difficult
bookproblem
q2.19-i
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Calculate the mass of a non-volatile solute (molar mass 40 g $mol^{–1}$) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
cbse
class12
chemistry
ch2
solutions
sec-b
easy
bookproblem
q2.18
asked
Aug 5, 2014
by
sreemathi.v
1
answer
The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a non-volatile solute in it.
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.17
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture of 26.0 g of heptane and 35 g of octane?
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.16
asked
Aug 5, 2014
by
sreemathi.v
1
answer
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