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Recent questions in Chemistry
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JEEMAIN and NEET
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Chemistry
Chemistry
Some Basic concepts in Chemistry
Atomic Structure
Classification of Elements and Periodicity in Properties
Chemical Bonding and Molecular Structure
Chemical Thermodynamics
Equilibrium
Redox Reactions
Hydrogen
s-Block Elements
p-Block Elements
P-Block elements (Group-13 and Group-14)
Hydrocarbons
Some Basic principles of Organic chemistry
Environmental Chemistry
States of Matter: Liquids and Gases
States of Matter: Solid State
Solutions
Electrochemistry
Surface Chemistry
General Principals and Processes of Isolation of Metals
p-Block elements (Group-15 to Group-18)
d-and-f-Block Elements
Co-ordination Compounds
Halogens
Oxygen: Alchohols, Phenols and Ethers
Nitrogen
Polymers
Biomolecules
Chemistry in everyday life
Practical Chemistry
Chemical Kinetics
Purification and Characterisation of Organic Compounds
Oxygen: Aldehydes, Ketones and Carboxylic Acids
The enolic form of acetone contains
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
easy
asked
Apr 4, 2014
by
meena.p
1
answer
If the reaction rate at a given temperature becomes slower. then
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
kossel-lewis-approach-to-chemical-bonding
medium
asked
Apr 4, 2014
by
meena.p
2
answers
Rate of a chemical reaction can be kept constant by
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
kossel-lewis-approach-to-chemical-bonding
medium
asked
Apr 4, 2014
by
meena.p
1
answer
The rate of a gaseous reaction is given by the expression $k[A][B]$. If the volume of the reaction vessel is suddenly reduced to $ \large\frac{1}{4}$ th of the initial volume , the reaction rate relating to original rate will be
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
difficult
asked
Apr 4, 2014
by
meena.p
1
answer
Diazonium salt decomposes as $ C_6H_5N^{+}_2CL^{-} \longrightarrow C_6H_5Cl+N_2$
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
medium
asked
Apr 4, 2014
by
meena.p
1
answer
The minimum energy required for molecules to enter into chemical reaction is called
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
difficult
asked
Apr 4, 2014
by
meena.p
1
answer
The molecularity of the reaction $6FeSO_4+3H_2SO_4+KClO_3 \longrightarrow KCl +3 Fe_2(SO_4)_3+3H_2O$ is
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
kossel-lewis-approach-to-chemical-bonding
medium
asked
Apr 4, 2014
by
meena.p
1
answer
$N_2$ and $O_2$ are converted into monoanions $N_2^{-}$ and $O_2^{-}$ respectively which of the following statem is wrong ?
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
medium
asked
Apr 4, 2014
by
meena.p
1
answer
Bond order of $N-O$ bonds in nitrate ions is :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
medium
asked
Apr 4, 2014
by
meena.p
1
answer
The dipole moment of $KCl$ is $3.336 \times 10^{-29}$ coulomb meter which indicates that it is a highly polar molecule. The inter atomic distance between $K^+$ and $Cl^{-}$ in this molecule is $2.6 \times 10^{-10}\;m$ Calculate the dipole moment of $KCl$ molecular if there were opposite charges of one fundamental unit located at each nucleus. Calculate percentage ionic character of $KCl$
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
difficult
asked
Apr 4, 2014
by
meena.p
1
answer
calculate the lattice energy of $KI,$ given that enthalphy of (i) sublimation of K is $90\;K\;J mol^{-1}$, (ii) dissociation of $I_2$ to $I^{-}$ is $213\;kJmol^{-1}$ (iii) ionisation of K to $K^{+}$ is $415\;kJ mol^{-1}$ (iv) electron affinity for I to $I^{-}$ is $-294.6 \;KJ\;mol^{-1}$ and $SH_f$ overall is $-327\;kJ\;mol^{-1}$
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
difficult
asked
Apr 4, 2014
by
meena.p
1
answer
The pressure exerted by 12g of an ideal gas at temperature $t^{\large\circ}C$ in a vessel of volume V litre is one atm. when the temperature is increased by 10 degree at the same volume , the pressure increases by $10\%$. Calculate the temperature t and volume V (molecular weight of the gas = 120 )
jeemain
chemistry
states-of-matter
unit5
class11
ideal-gas-equation
difficult
q178
asked
Apr 4, 2014
by
sharmaaparna1
1
answer
The experimental dipole moment of water molecule is $1.84\;D$ . Calculate the bond angle $H-O-H$ in water molecule , if dipole moment of OH bond is $1.5\;D$
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
difficult
asked
Apr 4, 2014
by
meena.p
1
answer
A diatomic molecule has a dipole moment equal to $1.2 \;D$ , If bond length is $1.0\;a^{\circ}$ What fraction of electronic charge 'e' exists on each atom ?
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
medium
asked
Apr 4, 2014
by
meena.p
1
answer
Which of the following are isoelectronic and isostructural ? $NO_3^{-},CO_3^{2-}, ClO_3^{-},SO_3$
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
hybridization
medium
asked
Apr 4, 2014
by
meena.p
1
answer
A square planar complex is formed by hybridisation of which atomic orbitals ?
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
hybridization
easy
asked
Apr 4, 2014
by
meena.p
1
answer
Identify the least stable ion amongst the following :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
kossel-lewis-approach-to-chemical-bonding
easy
asked
Apr 4, 2014
by
meena.p
1
answer
Statement 1: Band gap in germanium is small. Statement 2 : The energy spread of each germanium atomic energy level in infinitesimally small.
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
kossel-lewis-approach-to-chemical-bonding
medium
asked
Apr 4, 2014
by
meena.p
1
answer
Statement 1: p-hydroxybenzonic acid has a lower boiling point than $O- hydroxybenzonic acid. Statement 2: O-Hydroxybenzonic acid has intramolecular hydrogen bonding.
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
kossel-lewis-approach-to-chemical-bonding
medium
asked
Apr 4, 2014
by
meena.p
1
answer
Statement 1: $LiCl$ is predominantly a covalent compound. Statement 2: Electronegativity difference between $Li$ and $Cl$ is too small.
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
kossel-lewis-approach-to-chemical-bonding
medium
asked
Apr 4, 2014
by
meena.p
1
answer
Which one is most ionic?
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
ionic-or-electrovalent-bond
easy
asked
Apr 4, 2014
by
meena.p
1
answer
According to molecular orbitals theory which of the following statement about the magnetic character and bond order is correct regarding $O_2^{+}$?
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
difficult
asked
Apr 4, 2014
by
meena.p
1
answer
Among the following compounds the one that is polar and has the central atom with $SP^2$ hybridisation is
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
hybridization
medium
asked
Apr 4, 2014
by
meena.p
1
answer
The type of hybrid orbitals used by the chlorine atom in $ClO^{-}_2$ is
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
hybridization
difficult
asked
Apr 3, 2014
by
meena.p
1
answer
If a molecule $M X_3$ has zero dipole moment. the sigma bonding orbitals used by M. (atomic number <21) are
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
hybridization
easy
asked
Apr 3, 2014
by
meena.p
1
answer
The rate law of a reaction $A+B \to $ product is rate $=K [A]^n[B]^m$. On doubling the concentration of A and halving the concentration of B. Thr ratio of new rate to the earlier rate of reaction will be :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
medium
asked
Apr 3, 2014
by
meena.p
1
answer
Units of rate constant of first and zero order reaction in terms of molarity M are respectively :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
easy
asked
Apr 3, 2014
by
meena.p
1
answer
$t \large\frac{1}{4}$ can be taken as the time taken for concentration of reactant to drop to $\large\frac{3}{4}$ of its initial value. If the rate constant for a first order reaction is $K,$ then $t \large\frac{1}{4}$ can be written as
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
difficult
asked
Apr 3, 2014
by
meena.p
1
answer
The half - life period of a first order chemical reaction is $6.93$ minutes. The time required for the completion of $99\%$ of the chemical reaction will be $(\log 2 =0.301)$
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
difficult
asked
Apr 3, 2014
by
meena.p
1
answer
If I is the intensity of absorbed light and C is the concentration of AB for the photochemical process $AB+hr \to AB^ x$ the rate of formation of $AB^x$is directly proportional X :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
medium
asked
Apr 3, 2014
by
meena.p
1
answer
The temperature coefficient of a reaction is :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
vsepr(valence-shell-electron-pair-repulsion)theory
difficult
asked
Apr 3, 2014
by
meena.p
1
answer
The lightening of fire files is :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
medium
asked
Apr 3, 2014
by
meena.p
1
answer
Large increase in the rate of reaction due to rise in temperature is due to :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
vsepr(valence-shell-electron-pair-repulsion)theory
medium
asked
Apr 3, 2014
by
meena.p
1
answer
A gas filled freely collapsible balloon is pushed from the surface level of lake to a depth of 100 metre . Calculate what per cent of its original volume , the balloon finally have ? Assume ideal gas nature .
jeemain
chemistry
states-of-matter
unit5
class11
difficult
ideal-gas-equation
q177
asked
Apr 3, 2014
by
sharmaaparna1
1
answer
One Einstein = N $\times$ quanta of energy where N is :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
easy
asked
Apr 3, 2014
by
meena.p
1
answer
Equal weights of $CH_4$ and $O_2$ are mixed in an empty container of one litre at $27^{\large\circ}C$. Calculate the fraction of total pressure exerted by $O_2$.
jeemain
chemistry
states-of-matter
unit5
class11
kinetic-molecular-theory-of-gases
difficult
q176
asked
Apr 3, 2014
by
sharmaaparna1
1
answer
An open flask contains air at $27^{\large\circ}C$. Calculate temperature at which it should be heated so that , $\large\frac{1}{3}rd$ of air measured at $27^{\large\circ}C$ escapes out.
jeemain
chemistry
states-of-matter
unit5
class11
difficult
ideal-gas-equation
q175
asked
Apr 3, 2014
by
sharmaaparna1
1
answer
For an endothermic reaction where $\Delta H$ represents the enthalpy of the reaction in $kj/mol$. the minimum value for the energy of activation will be
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
vsepr(valence-shell-electron-pair-repulsion)theory
difficult
asked
Apr 3, 2014
by
meena.p
1
answer
A flask is of a capacity of one litre . What volume of air will escape from the flask if it is heated from $27^{\large\circ}C$ to $37^{\large\circ}C$? Assume pressure as constant.
jeemain
chemistry
states-of-matter
unit5
class11
difficult
ideal-gas-equation
q174
asked
Apr 3, 2014
by
sharmaaparna1
1
answer
The rate of a reaction gets doubled when the temperature changes from $7^{\circ}C$ to $17^{\circ}$ . By what factor will it change for the temperature change from $17^{\circ}C$ to $27^{\circ}C$
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
molecular-orbital-theory
difficult
asked
Apr 3, 2014
by
meena.p
1
answer
0.553 g of a boron - hydrogen compound created a pressure of 0.658 atm in a bulb of 407 mL at $100^{\large\circ}C$. Analysis showed it to $85.7\%$ boron . Calculate its molecular formula.
jeemain
chemistry
states-of-matter
unit5
ideal-gas-equation
class11
difficult
q173
asked
Apr 3, 2014
by
sharmaaparna1
1
answer
For a first order reaction , the plot of t against log C gives a straight with slope equal to :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
valence-bond-theory
difficult
asked
Apr 3, 2014
by
meena.p
1
answer
What would be the final pressure of $O_2$ in following experiment ? A collapsed polyethylene bag of 30 litre capacity is partially blown up by the addition of 10 litre of $N_2$ at 0.965 atm at 298K . Subsequently enough $O_2$ is pumped into bag so that at 298K and external pressure of 0.990 atm, the bag contains full 30 litre.
jeemain
chemistry
states-of-matter
unit5
ideal-gas-equation
class11
difficult
q172
asked
Apr 3, 2014
by
sharmaaparna1
1
answer
Half- life $(t_1)$ of the first order reaction and half-life $(t_2)$ of the second order reaction are equal. Hence ratio of the rate of the rate at te start of the reaction.
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
easy
asked
Apr 3, 2014
by
meena.p
1
answer
The chemical reaction $2O_3 \to 3O_2$ proceeds as follows : $ O_3 \rightleftharpoons O_2+O ......(fast) \qquad O+O_3 \to 2O_2 ....(slow)$. The rate law expression should be :
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
kossel-lewis-approach-to-chemical-bonding
easy
asked
Apr 3, 2014
by
meena.p
1
answer
The rate of the elementary reaction, $2NO+O_2 \to 2NO_2$ when the volume of the reaction vessel is doubled
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
kossel-lewis-approach-to-chemical-bonding
difficult
asked
Apr 3, 2014
by
meena.p
1
answer
Which of the following hydrocarbons has the lowest dipole moment?
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
bond-parameters
easy
asked
Apr 3, 2014
by
meena.p
1
answer
Hybridisation is defined as the phenomenon of mixing of orbitals of nearly the same energy so as to redistribute their energies and to give rise to new orbitals of equivalent energy. It is the valence shell atomic which get hybridised one of the electrons from an orbital in the ground state electronic configuration of the atom gets promoted to the next available orbital of higher energy resulting in an excited state electronic configuration with the appropriate number of half filled orbitals. The orbitale in the excited state undergo hybridisation giving hybrid orbilats of equivalent energy. Hybrid orbitals generally from either bonds or contain lone pair of electrons, they do not form $\pi$ bonds. Depending on the type of orbitals used the hybridisation may be categorized as $SP$(linear), $SP^2$ (trigonal planar ), $SP^3$(tetrahedral), $SP^3d$(trigonal bipyramidal), $SP^3d^2$(Octahedral), $SP^3d^3$ (Pentagonal bipyramid ).The strength of bonds formed by $S-S,P-P$ and $S-P$ overlap is in the order of
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
hybridization
easy
asked
Apr 3, 2014
by
meena.p
1
answer
Hybridisation is defined as the phenomenon of mixing of orbitals of nearly the same energy so as to redistribute their energies and to give rise to new orbitals of equivalent energy. It is the valence shell atomic which get hybridised one of the electrons from an orbital in the ground state electronic configuration of the atom gets promoted to the next available orbital of higher energy resulting in an excited state electronic configuration with the appropriate number of half filled orbitals. The orbitale in the excited state undergo hybridisation giving hybrid orbilats of equivalent energy. Hybrid orbitals generally from either bonds or contain lone pair of electrons, they do not form $\pi$ bonds. Depending on the type of orbitals used the hybridisation may be categorized as $SP$(linear), $SP^2$ (trigonal planar ), $SP^3$(tetrahedral), $SP^3d$(trigonal bipyramidal), $SP^3d^2$(Octahedral), $SP^3d^3$ (Pentagonal bipyramid ). Atomic orbitals of carbon in graphite have
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
hybridization
easy
asked
Apr 3, 2014
by
meena.p
1
answer
Hybridisation is defined as the phenomenon of mixing of orbitals of nearly the same energy so as to redistribute their energies and to give rise to new orbitals of equivalent energy. It is the valence shell atomic which get hybridised one of the electrons from an orbital in the ground state electronic configuration of the atom gets promoted to the next available orbital of higher energy resulting in an excited state electronic configuration with the appropriate number of half filled orbitals. The orbitale in the excited state undergo hybridisation giving hybrid orbilats of equivalent energy. Hybrid orbitals generally from either bonds or contain lone pair of electrons, they do not form $\pi$ bonds. Depending on the type of orbitals used the hybridisation may be categorized as $SP$(linear), $SP^2$ (trigonal planar ), $SP^3$(tetrahedral), $SP^3d$(trigonal bipyramidal), $SP^3d^2$(Octahedral), $SP^3d^3$ (Pentagonal bipyramid ). The non - linear structure is assumed by
jeemain
chemistry
physical-chemistry
class11
unit4
chemical-bonding-and-molecular-structure
hybridization
easy
asked
Apr 3, 2014
by
meena.p
1
answer
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