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Suggest the most important type of intermolecular attractive interaction in the following pair : n-hexane and n-octane
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.23-i
asked
Aug 5, 2014
by
sreemathi.v
1
answer
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
cbse
class12
chemistry
ch2
solutions
sec-a
medium
bookproblem
q2.22
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Two elements A and B form compounds having formula $AB_2$ and $AB_4$. When dissolved in 20 g of benzene ($C_6H_6$), 1 g of $AB_2$ lowers the freezing point by 2.3 K whereas 1.0 g of $AB_4$ lowers it by 1.3 K. The molar depression constant for benzene is 5.1 K $kg mol^{–1}$. Calculate atomic masses of A and B.
cbse
class12
chemistry
ch2
solutions
sec-c
medium
bookproblem
q2.21
asked
Aug 5, 2014
by
sreemathi.v
1
answer
A 5% solution (by mass) of cane sugar in water has freezing point of 271K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.20
asked
Aug 5, 2014
by
sreemathi.v
1
answer
A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate: vapour pressure of water at 298 K.
cbse
class12
chemistry
ch2
solutions
sec-c
difficult
bookproblem
q2.19-ii
asked
Aug 5, 2014
by
sreemathi.v
1
answer
A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate: molar mass of the solute
cbse
class12
chemistry
ch2
solutions
sec-c
difficult
bookproblem
q2.19-i
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Calculate the mass of a non-volatile solute (molar mass 40 g $mol^{–1}$) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
cbse
class12
chemistry
ch2
solutions
sec-b
easy
bookproblem
q2.18
asked
Aug 5, 2014
by
sreemathi.v
1
answer
The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a non-volatile solute in it.
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.17
asked
Aug 5, 2014
by
sreemathi.v
1
answer
Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture of 26.0 g of heptane and 35 g of octane?
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.16
asked
Aug 5, 2014
by
sreemathi.v
1
answer
An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. What is the molar mass of the solute?
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.15
asked
Aug 5, 2014
by
sreemathi.v
1
answer
What is meant by positive and negative deviations from Raoult's law and how is the sign of $\Delta_{mix}H$ related to positive and negative deviations from Raoult's law?
cbse
class12
chemistry
ch2
solutions
sec-c
difficult
bookproblem
q2.14
asked
Aug 5, 2014
by
sreemathi.v
1
answer
The partial pressure of ethane over a solution containing $6.56 × 10^{–3}$ g of ethane is 1 bar. If the solution contains $5.00 ×\times 10^{–2}$ g of ethane, then what shall be the partial pressure of the gas?
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.13
asked
Aug 4, 2014
by
sreemathi.v
1
answer
State Henry’s law and mention some important applications?
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.12
asked
Aug 4, 2014
by
sreemathi.v
1
answer
Why do gases always tend to be less soluble in liquids as the temperature is raised?
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.11
asked
Aug 4, 2014
by
sreemathi.v
1
answer
What role does the molecular interaction play in a solution of alcohol and water?
cbse
class12
chemistry
ch2
solutions
sec-a
medium
bookproblem
q2.10
asked
Aug 4, 2014
by
sreemathi.v
1
answer
A sample of drinking water was found to be severely contaminated with chloroform $(CHCl_3$) supposed to be a carcinogen. The level of contamination was 15 ppm (by mass): determine the molality of chloroform in the water sample.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.9-ii
asked
Aug 4, 2014
by
sreemathi.v
1
answer
A sample of drinking water was found to be severely contaminated with chloroform $(CHCl_3$) supposed to be a carcinogen. The level of contamination was 15 ppm (by mass): express this in percent by mass
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.9-i
asked
Aug 4, 2014
by
sreemathi.v
1
answer
An antifreeze solution is prepared from 222.6 g of ethylene glycol $(C_2H_6O_2$) and 200 g of water. Calculate the molality of the solution. If the density of the solution is $1.072 g mL^{–1}$, then what shall be the molarity of the solution?
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.8
asked
Aug 4, 2014
by
sreemathi.v
1
answer
A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass. Calculate the mass percentage of the resulting solution.
cbse
class12
chemistry
ch2
solutions
sec-b
easy
bookproblem
q2.7
asked
Aug 4, 2014
by
sreemathi.v
1
answer
How many mL of 0.1 M HCl are required to react completely with 1 g mixture of $Na_2CO_3$ and $NaHCO_3$ containing equimolar amounts of both?
cbse
class12
chemistry
ch2
solutions
sec-c
difficult
bookproblem
q2.6
asked
Aug 4, 2014
by
sreemathi.v
1
answer
A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is $1.2 g mL^{–1}$, then what shall be the molarity of the solution?
cbse
class12
chemistry
ch2
solutions
sec-c
difficult
bookproblem
q2.5
asked
Aug 4, 2014
by
sreemathi.v
1
answer
Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in aqueous solution. What should be the molarity of such a sample of the acid if the density of the solution is $1.504 g mL^{–1}$?
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.4
asked
Aug 4, 2014
by
sreemathi.v
1
answer
Define the following term : Mass percentage
cbse
class12
chemistry
ch2
solutions
sec-b
easy
bookproblem
q2.3-iv
asked
Aug 4, 2014
by
sreemathi.v
1
answer
Define the following term : Molarity
cbse
class12
chemistry
ch2
solutions
sec-b
easy
bookproblem
q2.3-iii
asked
Aug 4, 2014
by
sreemathi.v
1
answer
Define the following term : Molality
cbse
class12
chemistry
ch2
solutions
sec-b
easy
bookproblem
q2.3-ii
asked
Aug 4, 2014
by
sreemathi.v
1
answer
Define the following term : Mole fraction
cbse
class12
chemistry
ch2
solutions
sec-b
easy
bookproblem
q2.3-i
asked
Aug 4, 2014
by
sreemathi.v
1
answer
Give an example of a solid solution in which the solute is a gas.
cbse
class12
chemistry
ch2
solutions
sec-a
easy
bookproblem
q2.2
asked
Aug 4, 2014
by
sreemathi.v
1
answer
Define the term solution. How many types of solutions are formed? Write briefly about each type with an example.
cbse
class12
chemistry
ch2
solutions
sec-b
medium
bookproblem
q2.1
asked
Aug 4, 2014
by
sreemathi.v
1
answer
The Henry's law constant for the solubility of $N_2$ gas in water is $1.0\times 10^5$ atm.The mole fraction of $N_2$ in air is 0.8.The amount of $N_2$ from air dissolved in 10mol of water at 298K and 5 atm pressure is
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
difficult
asked
Jul 23, 2014
by
sreemathi.v
1
answer
Twenty grams of hemoglobin in 1L solution at 300K is separated from pure water by a semipermeable.At equilibrium,the height of solution (density $1gcm^{-3}$) in a tube dipped in solution is found to be 83.1mm higher than in the tube dipped in water.If $g=10ms^{-2}$ ,the molar mass of hemoglobin is about
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
difficult
asked
Jul 23, 2014
by
sreemathi.v
1
answer
A solution containing $8.6gL^{-1}$ of urea (molar mass $60gmol^{-1}$) is isotonic with a 5% solution of unknown solute.The molar mass of the solute will be
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
medium
asked
Jul 23, 2014
by
sreemathi.v
1
answer
The molar mass of sodium chloride determined by osmotic pressure would be
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
medium
asked
Jul 23, 2014
by
sreemathi.v
1
answer
The freezing point of a solution containing 36g of a compound (empirical formula : $CH_2O$) in 1.20 kg of water is found to be $-0.93^{\large\circ}C$.The molecular formula of the solute is
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
medium
asked
Jul 23, 2014
by
sreemathi.v
1
answer
A solution contains 10g of a solute and 116g of acetone at $30^{\large\circ}$C.Its vapour pressure is 290 Torr.If the vapour pressure of pure acetone is 300 Torr at $30^{\large\circ}$C,the molar mass of solute is
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The vapour pressure of a pure liquid A is 10.0 Torr at $27^{\large\circ}C$,One gram of B is dissolved in 20g of A,the vapour pressure is lowered to 90 Torr.If the molar mass of A is $200gmol^{-1}$,the molar mass of B is
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The vapour pressure of a solution of 5g of a nonelectrolyte in 100g water at a particular temperature is 2950 Pa and that of pure water at the same temperature is 3000 Pa.The molar mass of the solute is
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The vapour pressure of a solution having 2.0g of a solute X(molar mass $32gmol^{-1}$) in 100g of $CS_2$ (vapour pressure 854 Torr) is 848.9 Torr.The molecular formula of the solute is
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The molar mass of benzoic acid in benzene as determined by depression in freezing point method corresponds to
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
molar-mass
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The vapour pressure of a pure liquid A is 80 mmHg at 300K.It forms an ideal solution with liquid B.When the mole fraction of B is 0.4,the total pressure was found to be 88 mmHg.The vapour pressure of liquid A would be
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
A binary solution contains 4 mol of A and 6 mol of B.Its vapour pressure is found to be 460mm Hg.To this solution,when 10 mol of B is added,its vapour pressure becomes 480mm Hg.The vapour pressures of pure A and pure B,respectively,are
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The vapour pressure of n-hexane and n-heptane are 46 and 13mm Hg.If the vapour pressure of a solution of these two liquids is 38mmHg,the mole fraction of n-hexane in solution is
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The vapour pressure of pure benzene and toluence are 160 Torr and 60 Torr,respectively.The mole fraction of benzene in vapour phase in contact with equimolar solution of benzene and toluene would be
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The vapour pressure of pure liquid is 70 Torr at $27^{\large\circ}C$.The vapour pressure of a solution of this liquid and another liquid (mole fraction 0.2) is 84 Torr at $27^{\large\circ}C$.The vapour pressure of pure liquid B at $27^{\large\circ}C$ is
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
Which of the following solutions is expected to show negative deviations from Raoult's law?
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
Which of the following solutions is expected to show positive deviations from Raoult's law?
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The vapour pressure of a solvent in a solution is proportional to
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The vapour-pressure lowering of a solvent is proportional to
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
An azeotropic solution of two liquids has a boiling point higher than either of the boiling points of the two liquids when it
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
medium
asked
Jul 22, 2014
by
sreemathi.v
1
answer
Which of the following is true?
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
ideal-and-non-ideal-solutions
easy
asked
Jul 22, 2014
by
sreemathi.v
1
answer
The volume required to prepare 2.0L of 3.0M $H_2SO_4$ solution from 96% $H_2SO_4$ solution (density $1.83gmL^{-1}$) is
jeemain
chemistry
physical-chemistry
class12
ch2
solutions
composition-of-a-solution
easy
asked
Jul 22, 2014
by
sreemathi.v
1
answer
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