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Recent questions tagged electrochemistry

The EMF of electrode -concentration cell $Zn-Hg(C_1)/Zn^{+2}(aq)/Zn-Hg(C_2)$ at $25^{\large\circ}C$ if the concentration of zinc amalgam are $C_1=2g$ per 100g of mercury and $C_2=1g$ per 100g of mercury.

asked Feb 18, 2014 by sreemathi.v

1 answer

For the following galvanic cell the emf will be at $25^{\large\circ}C$.$Ag/AgCl(s),KCl(0.2M\parallel KBr(0.001M).AgBr(s)/Ag$.The solubility product of $AgCl$ & $AgBr$ are $2.8\times 10^{-10}$ and $3.3\times 10^{-13}$ respectively.

asked Feb 18, 2014 by sreemathi.v

1 answer

The standard reduction potential of $Ag^+/Ag$ electrode at 298K is 0.79V.$K_{sp}$ of Ag$^+$ is $8.7\times 10^{-17}$.Evaluate the standard reduction potential of $I^-/AgI/Ag$ electrode

asked Feb 18, 2014 by sreemathi.v

1 answer

The half potential of $Cl^{-1}(C_1)/AgCl/Ag$ electrode.Given the value of $E^0$ for $Ag^++e^-\rightarrow Ag$ and $K_{sp}$ of AgCl is

asked Feb 18, 2014 by sreemathi.v

1 answer

The emf of cell $Zn/ZnCl_2(0.05mol\;dm^{-3})/Ag^+/AgCl(s)/Ag$ is 1.015V at 298K,the silver electrode being positive,while the temperature coefficient of its emf is $-0.00492VK^{-1}$.Write down the equation for reaction occuring when the cell is allowed to discharge and calculate changes in entropy (s) accompanying this reaction,at 298K?

asked Feb 18, 2014 by sreemathi.v

1 answer

The emf of cell $Zn/ZnCl_2(0.05mol\;dm^{-3})/Ag^+/AgCl(s)/Ag$ is 1.015V at 298K,the silver electrode being positive,while the temperature coefficient of its emf is $-0.00492VK^{-1}$.Write down the equation for reaction occuring when the cell is allowed to discharge and calculate changes in free energy(G)?

asked Feb 18, 2014 by sreemathi.v

1 answer

Consider the relation,$2Ag^++Cd\rightarrow 2Ag+Cd^{+2}$ the standard electrode potentials for $Ag^+/Ag$ and $Cd^{+2}/Cd$ couples $0.8\;V$ and $0.04\;V$ respectively Then the emf of given reaction will be (if $[Cd^{+2}]=0.1M,[Ad^+]=1M)$

asked Feb 18, 2014 by sreemathi.v

1 answer

Consider the relation,$2Ag^++Cd\rightarrow 2Ag+Cd^{+2}$ the standard electrode potentials for $Ag^+/Ag$ and $Cd^{+2}/Cd$ couples 0.8V and 0.04V respectively.What is the standard potential for this reaction?

asked Feb 18, 2014 by sreemathi.v

1 answer

An electric current is passed through two electrolytic cells connected in series.One containing a solution of silver nitrate and the other solution of $H_2SO_4$.What volume of oxygen measured at $25^{\large\circ}C$ and 750mm of Hg would be liberated from $H_2SO_4$ if $8\times 10^{22}$ ions of $Ag^+$ are deposited from the silver nitrate solution?

asked Feb 17, 2014 by sreemathi.v

1 answer

An electric current is passed through two electrolytic cells connected in series.One containing a solution of silver nitrate and the other solution of $H_2SO_4$.What volume of oxygen measured at $25^{\large\circ}C$ and 750mm of Hg would be liberated from $H_2SO_4$ if 1mole and of $Ag^+$ are deposited from silver nitrate solution?

asked Feb 17, 2014 by sreemathi.v

1 answer

In an electrolysis experiment electric current was passed for 5hr through two cells connected in series.The first cell contains gold salt and second contains $CuSO_4$ solution.9.83g of gold was deposited in first cell.The magnitude of current in amperes is :-

asked Feb 17, 2014 by sreemathi.v

1 answer

In an electrolysis experiment electric current was passed for 5hr through two cells connected in series.The first cell contains gold salt and second contains $CuSO_4$ solution.9.83g of gold was deposited in first cell.If the oxidation number of Au is +3,find the amount of copper deposited in second cell

asked Feb 17, 2014 by sreemathi.v

1 answer

The passage of a constant current through a dilute solution of sulfuric acid with platinum electrodes,for the resulted in liberation of 336ml of mixed hydrogen and oxygen ,reduced to S.T.P.Then the strength of current is

asked Feb 17, 2014 by sreemathi.v

1 answer

$CuSO_4$ solution(250ml) was electrolysed using a platinum anode and a copper cathode.At constant current of 2mA was passed for 16 minutes.It was found that after electrolysis the absorbance of this solution was reduced to 50% of its original value.Then the concentration of copper sulphate in solution to begin with is

asked Feb 17, 2014 by sreemathi.v

1 answer

The standard reduction potential of $Cu^{+2}/Cu$ and $Ag^+/Ag$ electrode are 0.337 and 0.799Volt respectively for this positive emf galvanic cell,for what concentration of $Ag^+$ will be emf of cell at $25^{\large\circ}C$ be zero,if the concentration of $Cu^{+2}$ is 0.01M?

asked Feb 17, 2014 by sreemathi.v

1 answer

A zinc rod is placed in $0.1\;M$ solution of $ZnSO_4$ at $25^{\large\circ}$C.Assuming that the salt is dissociated to the extent of $95\%$ at this dilusion ,then the potential of electrode at this temperature.Given that $E^0_{Zn^{2+}/Zn}=0.76Volts$.

asked Feb 17, 2014 by sreemathi.v

1 answer

A solution of a salt of a metal of atomic weight $'\lambda'$ was electrolysed for 150minutes with 0.15A of current .The weight of metal deposited was 0.783g.Find X,the specific heat of metal=0.057Cal/$g^{\large\circ}C$.According to Dulong-Petit's law,approximate atomic weight of a metal $X$ specific heat=6.4

asked Feb 17, 2014 by sreemathi.v

1 answer

The EMF of cell is : $Pt/H_2/CH_3COOH(0.1M)\parallel NH_4OH(0.01M)/H_2/Pt$.$K_a$ for $CH_3COOH=1.8\times 10^{-5}$ and $K_b$ for $NH_4OH=1.8\times 10^{-5}$

asked Feb 17, 2014 by sreemathi.v

1 answer

EMF of following cell is 0.67V at 298K $Pt/H_2(1atm)/H^+(pH=X)\parallel KCl(1N)/Hg_2Cl_2(s)/Hg$.Calculate pH of anode compartment.Given : $E^0_{Cl^-/Hg^2Cl_2/Hg}=0.28V$.

asked Feb 17, 2014 by sreemathi.v

1 answer

By how much is oxidizing power of $MnO_4^-/Mn^{+2}$ couple decreases if the $H^+$ concentration is decreased from 1M to $10^{-4}$M at $25^{\large\circ}C$ .Assume other species have no change in concentration.

asked Feb 17, 2014 by sreemathi.v

1 answer

The EMF of cell $Ag/AgCl(K_{sp})(saturated\; sol)\parallel Cl^-(C_1)/AgCl(K_{sp}/Ag)$ is given by

asked Feb 17, 2014 by sreemathi.v

1 answer

How many Faradays are required to reduce on mole of $MnO_4^-$ to $Mn^{+2}$

asked Feb 17, 2014 by sreemathi.v

1 answer

The $E_{cell}$ in which the reaction :$MnO_4^-+Fe^{+2}+H^+\rightarrow Mn^{+2}+Fe^{+3}+H_2O$ occurs is 0.59V at $25^{\large\circ}C$.The equilibrium constant for the reaction is

asked Feb 17, 2014 by sreemathi.v

1 answer

$Zn/Zn^{+2}(C_1)\parallel Zn^{+2}(C_2)/Zn$.For this cell $\Delta G$ is -ve if

asked Feb 17, 2014 by sreemathi.v

1 answer

Which of the following facts is not true?

asked Feb 17, 2014 by sreemathi.v

1 answer

If $E^0_{Fe^{+2}/Fe}$ is $X_1$,$E^0_{Fe^{+3}/Fe}$ is $X_2$ then $E^0_{Fe^{+3}/Fe^{+2}}$ will be

asked Feb 17, 2014 by sreemathi.v

1 answer

A solution containing one mole per litre each of $Cu(NO_3)_2,AgNO_3,Hg_2(NO_3)_2,Mg(NO_3)_2$ is being electrolysed by using inert electrodes.The values of standard potentials are $E^0_{Ag^+/Ag}=0.8V$,$E^0_{Hg^{+2}/Hg}=0.79V$,$E^0_{Cu^{+2}/Cu}=0.34V$,$E^0_{Mg^{+2}/Mg}=-2.3V$ with increasing voltage the sequence of deposition of metals on the cathode will be

asked Feb 17, 2014 by sreemathi.v

1 answer

A current of 2A when passed for five hour through a molten metal salt,it deposits 22.2g of metal of atomic weight 177.The oxidation state of metal in metal salt is

asked Feb 17, 2014 by sreemathi.v

1 answer

The standard reduction potentials at 298K for following half reaction are given against each.
$Zn^{+2}(aq)+2e^-\leftrightharpoons 2n(s)=-0.762$
$Cr^{+3}(aq)+3e^-\leftrightharpoons Cr(s)=-0.740$
$2H^+(aq)+3e^-\leftrightharpoons H_2(g)=0$
$Fe^{+3}(aq)+e^-\leftrightharpoons Fe^{+2}(aq)=0.770$.

Which is the strongest reducing agent ?

asked Feb 17, 2014 by sreemathi.v

1 answer

Four moles of electrons were transferred from anode to cathode in an experiment of electrolysis of water.The total volume of two gases produced will be approximately(in litre) at STP.

asked Feb 17, 2014 by sreemathi.v

1 answer

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