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Answers posted by meena.clay6
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The phase difference between the instantaneous velocity and acceleration of a particle executing simple harmonic motion is :-
answered
Apr 14, 2020
Solution :Velociyt $v= v_0 sm wt$accleration $=\large\frac{dv}{dt}$$=a=a_0cos wt$$\therefore $ phase...
0
votes
The frequency of a light wave in a material is $2 \times 10^{14}$ Hz and wavelength is $5000$ Å. The refractive index of material will be:-
answered
Apr 14, 2020
solution :Refractive index $= \large\frac{\text{Velocity in air}}{\text{velocity in medium }}$$\qqua...
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votes
A black body is at $727^{\circ}C$. It emits energy at a rate which is proportional to:
answered
Apr 14, 2020
Solution :$E= Radiation \alpha T^4$ Where T is in kelvin$E \alpha (727+273)^4$$E \alpha 1000^4$
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votes
For moon, its mass is 1/81 of earth mass and its diameter is 1/3.7 of earth dia.If acceleration due to gravity at earth surface is $9.8 m/s ^{2}$ then at moon its value is :
answered
Apr 14, 2020
Solution :Accleration due to gravity $g =\large\frac{M}{R^2}$$g \alpha \large\frac{M}{R^2}$$\large\f...
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Excess of $KI$ reacts with $CuSO_4$ solution and then $Na_2S_2O_3$ solution is added to it. Which of the statements is incorrect for this reaction ?
answered
Apr 13, 2020
Solution :$2CuSO_4+4Kl \to Cu_2l_2+ 2 K_2SO_4+I_2$This liberated $I_2$ is titrated with&n
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The $E^{\circ}_{M^{+3}/M^{2+}}$ values for $Cr, \; Mn, \; Fe$ and $Co$ are $-0.41, \; +1.57, \; + 0.77$ and $+1.97 /;\;V$ respectively. For which one of these metals the change in oxidation state form $+2$ and $+3$ is easiest ?
answered
Apr 13, 2020
Solution :More the negative value of standard reduction potential, higher is the reducing power and ...
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The soldiers of Napolean army while at Alps during freezing winter suffered a serious problem as regards to the tin buttons of their uniforms. White metallic tin buttons got converted to grey powder. This transformation is related to
answered
Apr 13, 2020
Solution :This transformation is related to a change in crystalline structure of tin. This change in...
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Aluminium chloride exists as dimer, $Al_2Cl_6$ in solid state as well as in solution of non-polar solvents such as benzene. When dissolved in water, it gives
answered
Apr 13, 2020
Solution :$AlCl_3$ is covalent but in water, it becomes ionic to larger hydration energy of $Al^{3+}...
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votes
Beryllium and aluminium exhibit many properties which are similar. But the two elements differ in
answered
Apr 9, 2020
Solution :Due to diagonal relationship, Be and Al exhibits similar properties But covalency of&...
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Which one of the following ores is best concentrated by froth-floatation method ?
answered
Apr 9, 2020
Solution :Galena (ZnS) is a sulphide ore. Galena is best concentrated by fr...
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One mole of magnesium nitride on the reaction with an excess of water gives
answered
Apr 9, 2020
One mole of magnesium nitride on the reaction with an excess of water gives two moles of ammonia and...
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votes
Identify the correct statements regarding enzymes
answered
Apr 9, 2020
solution :Normal optimum temperature of enzymes is between $25^{\circ}C$ to $40^{\circ}C$. Henc...
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votes
Which one the following statement regarding helium is incorrect ?
answered
Apr 9, 2020
Solution :Helium is twice as heavy as hydrogen; its lifting power is 92% of that of hydrogen. H...
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In a cell that utilises the reaction $Zn(s) + 2H^+(aq) \to Zn^{2+} (aq) + H_2(g)$ addition of $H_2SO_4$ to cathode compartment, will
answered
Apr 9, 2020
Solution :$Zn_{(s)}+2H^{+}_{(aq)} \rightleftharpoons$$ Zn^{2+}_{(aq)}+H_2{(g)}$$E_{cell}=E^{\circ}_{...
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votes
The limiting molar conductivities $\bigwedge^{\circ}$ for $NaCl,\;KBr$ and $KCl$ are $126, \;152$ and $150\; S\; cm^2 \; mol^{-1}$ respectively. The $\bigwedge^{\circ}$ for $NaBr$ is
answered
Apr 9, 2020
Solution :$\bigwedge^{\circ} Nacl =\bigwedge^{\circ}_{Na}+\bigwedge^{\circ} _{CL^{-}}$ -------------...
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The enthalpies of combustion of carbon and carbon monoxide are $-393.5$ and $-283 \; kJ\; mol^{-1}$ respectively. The enthalpy of formation of carbon monoxide per mole is
answered
Apr 9, 2020
Solution :Combustion of Carbon:$C + O_2 \to CO_2 ; \Delta H1 = – 393.5 kJ / mole$Combustion of Carbo
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The standard e.m.f of a cell, involving one electron change is found to be 0.591 V at $25^{\circ}C$. The equilibrium constant of the reaction is $(F = 96,500\;C\;mol^{-1} : R = 8.314 \; JK^{-1}\;mol^{-1})$
answered
Apr 9, 2020
Solution : $E_{cell}=E^{\circ} _{cell}- \large\frac{0.0591}{n}$$\log K_c$$0=0.591-\large\frac{0.0591...
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votes
The molar solubility products is $K_{sp}$. 's' is given in terms of $K_{sp}$ by the relation
answered
Apr 9, 2020
Solution : $MX_4 \leftrightharpoons M^{+} +4X^{-}$If Solubility is s, then $K_{sp} =[M^{+}][X^{-}]^4...
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votes
Consider the following $E^{\circ}$ values
$E^{\circ}_{Fe^{3+}/Fe^{2+}} = 0.77V$
$E^{\circ}_{Sn^{2+}/Sn} = -0.14V$
Under standard conditions the potential for the reaction
$Sn(s) + 2Fe^{3+}(aq) \to 2Fe^{2+} (aq) + Sn^{2+}(aq)$ is
answered
Apr 9, 2020
Solution :$E_{cell}^0 =E(OPS_n/Sn^{2+})+E_{Fe^{2+}}+Fe^{2+}$$\qquad= 0.14 +0.77 =0.91\;V$
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votes
The rate equation for the reaction $2A + B \to C$ is found to be : rate $k[A][B]$. The correct statement in relation to this reaction is that the
answered
Apr 8, 2020
Solution :From the rate equation rate =k[A][B], we can say that the reaction is first order in ...
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votes
The equilibrium constant for the reaction $N_2(g) +O_2(g) \leftrightharpoons 2NO(g)$ at temperature $T$ is $4 \times 10^{-4}$. The value of $Kc$ for the reaction $NO(g) \leftrightharpoons \frac{1}{2} N_2 (g) + \frac{1}{2} O_2 (g) $ at the same temperature is
answered
Apr 8, 2020
Solution :$H_2(g) +O_2(g) \to 240(g)$$K_1= 4 \times 10^{-4}$$NO= \large\frac{1}{2}$$H_2(g) +\large\f...
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votes
For the reaction, $CO(g) + Cl_2 (g) \leftrightharpoons COCl_2(g) $ the $\frac{K_p}{K_c}$ is equal to
answered
Apr 8, 2020
Solution :$K_p=K_c \times (RT)^{\Delta ng}$where:$K_p$= equilibrium constant in terms of pressure$K_...
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votes
What is the equilibrium expression for the reaction $P_{4(s)} + 5O_{2(g)} \leftrightharpoons P_4O_{10 (s)} $?
answered
Apr 8, 2020
Solution :The equilibrium reaction is $H_2(g) +I_2(g) \to 2HI(g)$Assume that the total volume of the...
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votes
In first order reaction, the concentration of the reactant decreases from 0.8 M to 0.4 M in 15 minutes. The time taken for the concentration to change from 0.1 M to 0.025 M is
answered
Apr 7, 2020
Solution :The concentration of the reactant decreases from 0.8M to 0.4M in 15 minutes,i.e. t1/2...
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votes
In hydrogen-oxygen fuel cell, combustion of hydrogen occurs to
answered
Apr 7, 2020
Solution :Direct conversion of chemical energy to electric energy can be made considerably more effi...
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votes
An ideal gas expands in volume from $1 \times 10^{-3} m^{3} $ to $1 \times 10^{-2} m^3$ at 300 K against a constant pressure of $1 \times 10^5 \; Nm^{-2}$. The work done is
answered
Apr 7, 2020
Solution :Answer: -0.9 kJ$W = - P \Delta V$$P = 10^5 Nm^{-2}$ = 1 atm$\Delta V$ = 10 -1 = 9 Litres [...
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votes
What type of crystal defect is indicated in the diagram below ?
answered
Apr 7, 2020
Solution :Schottky defect is indicated in the diagram as equal number of sodium cation and chloride ...
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votes
Which of the following liquid pairs shows a positive derivation from Raoult's law?
answered
Apr 7, 2020
Solution :Benzene in methanol breaks the H - bonding of the alcohol making its boiling point decreas...
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votes
For which of the following parameters the structural isomers $C_2H_5OH$ and $CH_3OCH_3$ would be expected to have the same values ?
(Assume ideal behaviour)
answered
Apr 7, 2020
Solution :In $CH_3CH_2OH$, there is intermolecules H- bonding while it is absent in isomeric ether $...
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votes
To neutralize completely $20\; mL$ of $0.1\; M$ aqueous solution of phosphorous acid $(H_3PO_3)$, the volume of $0.1 \; M$ aqueous $KOH$ solution required is
answered
Apr 7, 2020
Solution :$H_3PO_3$ is a diabasic acid (containing two ionizable protons attached to O directly)$H_3...
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votes
$6.02 \times 10^{20}$ molecules of urea are present in $100\; ml$ of its solution. The concentration of urea solution is
answered
Apr 7, 2020
Solution :Moles of urea $= \large\frac{6.02 \times 10^{20}}{6.02 \times 10^{23}}$$=10^{-3}\; moles$C...
0
votes
The conjugate base of $H_2PO_4^-$ is
answered
Apr 7, 2020
Solution :The concept of conjugate Acid-Base pair was given by Lowry-Bronsted Theory.According to th...
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votes
In Vander Waals equation of state of the gas law, the constant 'b' is a measure of
answered
Apr 6, 2020
Solution :b = $4N\times V$i.e total volume occupied by molecules one mole of gas in motionHence answ...
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votes
Which among the following factors is the most important in making fluorine the strongest oxidizing halogen ?
answered
Apr 6, 2020
Elecrons gain enthalpy- when an electron is added to neutral gaseous atom to convert it into a negat...
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votes
Which one of the following aqueous solutions will exhibit highest boiling point ?
answered
Apr 6, 2020
Solution :Greater the number of solute particles in the solution, higher the elevation in boiling po...
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votes
The maximum number of $90^{\circ}$ angles between bond pair of electrons is observed in
answered
Apr 6, 2020
Solution :( B ) $sp^3d^2$ hybridization$sp^3d^2$ hybridization has an octahedral structure such that...
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votes
As the temperature is raised from $20^{\circ}C$ to $40^{\circ}C$, the average kinetic energy of neon atoms changes by a factor of which of the following?
answered
Apr 6, 2020
Kinetic Energy = $\large\frac{3}{2}RT$$E_1 = \large\frac{3}{2}\times R\times293$$E_2 = \large\frac{3...
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votes
Of the following outer electronic configurations of atoms, the highest oxidation state is achieved by which one of them ?
answered
Apr 6, 2020
Solution :+7 state can be achieved by give d-electrons and two s-electrons.Hence (a) is the correct ...
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votes
Which one of the following has the regular tetrahedral structure ?
answered
Apr 6, 2020
Solution :$BF_{4−}$ has regular tetrahedral structure,
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votes
The states of hybridization of boron and oxygen atoms in boric acis$(H_3BO_3)$ are respectively
answered
Apr 6, 2020
solution :Each oxygen atom is $sp_3$ hybridised. There are six electrons in the outermost shell of o...
0
votes
The formulation of the oxide ion $O^{2-} (g)$ requires first an exothermic and then an endothermic step as shown below
$O(g) + e^-O^-(g) \Delta H^{\circ} = -142 \; kJ\; mol^{-1}$
$O^-(g) + e^-O^{2-} (g) \Delta H^{\circ} = 844\;kJ\; mol^{-1}$
answered
Apr 6, 2020
Solution :Electron affinity is a measure of the attraction between the incoming electron and the nuc...
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votes
The bond order in NO is 2.5 while that in $NO^+$ is 3. Which of the following statements is true for these two species ?
answered
Apr 6, 2020
Solution :Higher the bond order, shorter will be the bond length. Thus, NO+ is having higher bo...
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votes
Among $Al_2O_3, SiO_2, P_2O_3$ and $SO_2$ the correct order of acid strength is
answered
Apr 6, 2020
Solution :As electronegativity difference between element and oxygen decreases the acidic character ...
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votes
Which one of the following sets of ions represents the collection of isoelectronic species ?
answered
Apr 6, 2020
Each of $K^+,Cl^-,Ca^{2+},Sc^{3+}$ has 18 electrons.Hence (b) is the correct answer.
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votes
The correct order of bond angles (smallest first) in $H_2S, \; NH_3, \; BF_3$ and $SiH_4$ is
answered
Apr 6, 2020
Solution :Bond angle in $SiH_4$ is $109. 28^1 (sp_3$-hybridisation with no lone ...
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votes
The wavelength of the radiation emitted, when in hydrogen atom electron falls from infinity to stationary state , would be (Rydberg constant = $1.097 \times 10^7\; m^{-1}$)
answered
Apr 6, 2020
$\large\frac{1}{\lambda}=$$R_H\big[\large\frac{1}{\infty}-\frac{1}{1^2}\big]$$\therefore \lambda=\la...
0
votes
Which one of the following ions has the highest value of ionic radius ?
answered
Apr 6, 2020
Solution :where z/e ratio increases, the size decreases and when z/e ratio decreases the size increa...
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votes
Consider the ground state of Cr atom (Z = 24). The number of electrons with the azimuthal quantum numbers $l = 1$ and $2$ are respectively
answered
Apr 6, 2020
Solution :Cr(Zn=24)electronic configuration is $:1_{s2}2_{s2}2_{p6}3_{s2}3_{p6}4_{s1}3_{d5}$So, numb...
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votes
Which of the following sets of quantum numbers is correct for an electron in 4f orbital ?
answered
Apr 6, 2020
Solution :For 4f orbital electrons,n = 4l = 3 (because 0 1 2 3 )m = +3, +2, +1, ...
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votes
The correct structure of tribromooctaoxide is :-
answered
Apr 6, 2020
solution :https://clay6.com/mpaimg/3_c20.jpg
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