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Answers posted by meena.clay6
Questions
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Compound A, $C_8 H_{10}O$, is found to react with $NaOI$ (produced by reacting Y with NaOH) and yield a yellow precipitate with characteristic smell.
A and Y are respectively
answered
Apr 2, 2020
Solution :https://clay6.com/mpaimg/5_c3.jpg
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Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to their
answered
Apr 2, 2020
Solution :Carboxylic acids are higher boiling liquids than aldehydes, ketones and even alcohols of c...
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votes
In the reaction
The electrophile involved is
answered
Apr 2, 2020
Solution :https://clay6.com/mpaimg/4_c1.jpg
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Which one of the following elements is unable to form $MF_6^{3-}$ ion ?
answered
Mar 31, 2020
Solution :Boron does not have vacant d-orbitals in its valence shell, so it cannot extend its covale...
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The correct order of N-compounds in its decreasing order of oxidation states is
answered
Mar 31, 2020
Solution :Oxidation state of N in $HNO_3=+5$Oxidation state of N in $NO=+2$Oxidation state of N in $...
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In the structure of $CIF_3$, the number of Ione pair of electrons on central atom 'Cl' is
answered
Mar 31, 2020
solution :In the structure of $ClF_3$, the number of lone pairs of electrons on central atom Cl is t...
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The correct order of atomic radii in group 13 elements is
answered
Mar 31, 2020
Solution :Ga is slightly smaller than Al due poor shielding of d e- so $Z_{eff}$. increasing. Atomic...
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Considering Ellingham diagram, which of the following metals can be used to reduce alumina ?
answered
Mar 31, 2020
Solution :Mg has more $-\Delta G$ value then alumina. So it will be in the lower part of Ellingham d...
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Which of the following statements is not true for halogen ?
answered
Mar 31, 2020
Solution :Due to high electronegativity and small size, F forms only one oxoacid, HOF known as Fluor...
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Consider the following species :
$CN^+, CN^-, NO$ and $CN$
Which one of these will have the highest bond order ?
answered
Mar 31, 2020
Solution :$NO:B.O= \large\frac{10-5}{2}$$=2.2$$CN^{-}:B.O=\large\frac{10-4}{2}$$=3$$CN : B.O =\large...
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Which one is a wrong statement ?
answered
Mar 31, 2020
Solution : Orbital angular momentum $=\sqrt{l(l+1)} \large\frac{h}{2\pi}$For 's' orbital l=0 Orbital...
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Iron exhibits bcc structure at room temperature. About $900^oC$, it transforms to fcc structure. The ratio of density of iron at room temperature to that at $900^oC$ (assuming molar mass and atomic radii of iron remains constant with temperature) is
answered
Mar 31, 2020
BCC $4r= \sqrt{3a}$$a= \large\frac{4r}{\sqrt{3}}$FCC$4r=\sqrt{2a}$$a= \large\frac{4r}{\sqrt 2}$$\lar...
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Magnesium reacts with an element (X) to form an ionic compoun. If the ground state electronic configuration of (X) is $1s^2 2s^2 2p^3$, the simplest formula for this compound is
answered
Mar 31, 2020
Solution :Element (X) electronic configuration $1s^22s^22p^3$So, valency of X will be 3.Valency of $...
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Which of the followng carbocations is expected to be most stable ?
answered
Mar 30, 2020
Solution :$NO_2$ group shows electron-withdrawing (-I) effect. The carbocations directly attached to...
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Which of the following molecules represents the order of hybridisation $sp^2, sp^2, sp, sp$ from left to right atoms?
answered
Mar 30, 2020
Solution :https://clay6.com/mpaimg/1_c54.jpg
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The correct difference between first and second order reactions is that
answered
Mar 30, 2020
Solution :For first order$t_{1/2}$ is independent from initial concentrationFor second order$t_{1/2}...
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In which case in number of molecules of water maximum ?
answered
Mar 30, 2020
Solution :The maximum number of water molecules corresponds to the maximum number of moles of water....
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Among $CaH_2, BeH_2, BaH_2$, the order of ionic character is
answered
Mar 30, 2020
Solution :The ionic character of a bond is dependent on the electronegativities of the atoms involve...
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Consider the change in oxidation state of Bromine corresponding to different emf values as shown in the diagram below :
$BrO_4^- \xrightarrow{1.82 V} BrO_3^- \xrightarrow{1.5 V} HBrO \xrightarrow{1.595 V} Br_2 \xrightarrow{1.0652 V} Br^-$
Then the species undergoing disproportionation is
answered
Mar 30, 2020
Solution :$BrO_3 \qquad \underrightarrow{-1.5\;V} \qquad HBrO$Reverse above equation $HBrO \qquad \u...
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Which one of the following conditions will favour maximum formation of the product in the reaction,
$A_2 (g) + B_2 (g) \rightleftharpoons X_2 (g) \Delta_f H = - X\;kJ$ ?
answered
Mar 30, 2020
Solution :$A_2(g)+B_2(g) \leftrightharpoons X_2(g) \Delta rH=−XkJ$On increasing pressure equilibrium
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For the redox reaction
$MnO_4^- + C_2O_4^{2-} + H^+ \to Mn^{2+} + CO_2 + H_2O$
The correct coefficients of the reactants for the balanced equation are
answered
Mar 30, 2020
Solution :The unbalanced redox reaction is $MnO_4−+C_2O_{42−}+H^{+} \to Mn_2++CO_2+H_2O$ Balance C a
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The correction factor 'a' to the ideal gas equation corresponds to
answered
Mar 30, 2020
Solution :Force of attraction between the gas molecules In the real gas eqation $\bigg( P+\large\fra...
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When initial concentration of the reactant is doubled, the half-life period of a zero order reaction
answered
Mar 30, 2020
Solution :The half-life period of a zero order reaction is doubled.$(t/2)_{zero}=\large\frac{[A]_0}{...
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The bond dissociation energies of $X_2, Y_2$ and $XY$ are in the ratio of 1 : 0.5 : 1. $\Delta H$ for the formation of $XY$ is $-200\; kJ \;mol^{-1}$. The bond dissociation energy of $X_2$ will be :
answered
Mar 30, 2020
Solution :Let B.E of $x_2Y_2$ and xy are $xk J mol^{-1}$ and $xkj\;mol^{-1}$ respectively $\large\fr...
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Which oxide of nitrogen is not a common pollutant introduced into the atmosphere both due to natural and human activity?
answered
Mar 30, 2020
Solution :$N_2O_5$ is not a common pollutant introduced into a atmosphere both due to natural and hu...
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votes
The compound $C_7H_8$ undergoes the following reactions:
$C_7H_8 \xrightarrow{3Cl_2/ \Delta} A \xrightarrow{Br_2/Fe} B \xrightarrow{Zn/ HCl} C$
The product 'C' is
answered
Mar 30, 2020
Solution :https://clay6.com/mpaimg/1_c53.jpg
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Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to gaseous hydrocarbon containing less than four carbon atoms. (A) is
answered
Mar 30, 2020
solution :Hydrocarbon (A) is methane $(CH_4)$. It reacts with bromine by substitution to form methyl...
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The compound A on treatment with Na gives B, and with $PCl_4$ gives C, B and C react together to give diethyl ether. A, B and C are in the order
answered
Mar 30, 2020
Solution : https://clay6.com/mpaimg/c52.jpg
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Nitrogen of aniline in strong acidic medium also gives m-nitroaniline because
answered
Mar 30, 2020
Solution :https://clay6.com/mpaimg/c51.jpgIn acidic medium aniline is protonated to form anilinium i...
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Regarding cross-linked or network polymers, which of the following statements is incorrect ?
answered
Mar 30, 2020
Solution :Cross linked of network polymers are usually formed from bi-functional and tri-functional ...
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A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. $H_2SO_4$. The evolved gaseous mixture is passed through KOH pellets. Weight (in g) of the remaining product at STP wil be
answered
Mar 30, 2020
Solution :$HCOOH \longrightarrow CO +H_2O$$(moles)_i= \large\frac{2.3}{46}=\frac{1}{20} \qquad 0 \q...
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The diffrence between amylose and amylopectin is
answered
Mar 30, 2020
Solution :Amylose and amylopectin are present side by side and interspersed in the starch granule. T...
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Which of the following oxides is most acidic in nature ?
answered
Mar 30, 2020
Solution :The acidic character of oxides increases across the period while it decreases down the gro...
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Which of the following reactions is appropriate for converting acetamide to methanamine ?
answered
Mar 27, 2020
https://clay6.com/mpaimg/c50.jpgIt is called Hoffman bromamide reaction.
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The species, having bond angles of $120^o$ is
answered
Mar 27, 2020
$BCl_3$ is trigonal planar and hence the bond angle is $120^{\circ}$
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If molality of the dilute solution is doubled, the value of molal depression constant $(K_f)$ will be
answered
Mar 27, 2020
If molality of the dilute solution is doubled, the value of molal depression constant $(K_f)$ remain...
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votes
Which one is the correct order of acidity ?
answered
Mar 27, 2020
Solution :Acidic strength $\alpha$ Electronegativity of Carbon $\alpha \%$ s-characterHence the orde...
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The element Z = 114 has been discovered recently. It will belong to which of the following family/group and electronic configuration ?
answered
Mar 27, 2020
Solution :$Z=114[Rn]^{86}7s^{2}5f^{14}6d^{10}7p^2$14thgp . (carbon family)As present set of periodic...
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Ionic mobility of which of the following alkali metal ions is lowest when aqueous solutions of their salts are put under an electric filed?
answered
Mar 27, 2020
Solution :$Li^{+}$ being smallest, has maximum charge density. Li+ is most heavily hydrated among al...
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votes
Which one of the following statements is not correct ?
answered
Mar 27, 2020
The value of equilibrium constant is not changed in the presence of a catalyst in the reaction at eq...
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$HgCl_2$ and $I_2$ both when dissolved in water containing $I^–$ ions pair of species formed is :
answered
Mar 27, 2020
Solution :In a solution containing $HgCl_2,I_2$ and $I^−$, both $HgCl_2$ and $I_2$ complete for $I^{
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Which of the following pairs of compounds is isoelectronic and isostructural ?
answered
Mar 27, 2020
Solution :Total number of valence electrons are equal in both the species and both the species exhib...
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For a given reaction, $\Delta H = 35.5\; KJ\; mol^{-1}$ and $\Delta S = 83.6 \; JK^{-1} mol^{-1}$. The reaction is spontaneous at : (Assume that $\Delta H$ and $\Delta S$ do not vary with temperature)
answered
Mar 27, 2020
Solution :Accoding to Gibbs-Helmholtz equation,Gibbs energy $(\Delta G)= \Delta H−T \Delta S$Where ,
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Correct increasing order for the wavelengths of absorption in the visible region for the complexes of $Co^{3+}$ is -
answered
Mar 27, 2020
Solution :$\Delta E \alpha$ field of ligand strength $\alpha \large\frac{1}{\alpha}$correct order o...
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A gas is allowed to expand in a well insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy $\Delta U$ of the gas in joules will be -
answered
Mar 27, 2020
Solution : The change in the internal energy is given by the following expression.$\Delta U=q+W$Sinc...
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votes
In the electrochemical cell -
$Zn|ZnSO_4 \; (0.01 M) || CuSO_4 \; (1.0 M) | Cu$, the emf of this Daniel cell is $E_1$. When the concentration of $ZnSO_4$ is changed to $0.1 M$ and that of $CuSO_4$ changed to $0.01 M$, the emf changes to $E_2$. From the followings, which one is the relayionship between $E_1$ and $E_2$ ? (Given , $\frac{RT}{F} = 0.059$)
answered
Mar 27, 2020
Solution : $Zn| ZnSO_4(0.01\;M) || CuSO_4(1.0\;M) | Cu$$\therefore E_1=E_{cell}^0 - \large\frac{2.30...
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Predict the correct intermediate and product in the following reaction :
$H_3C - CH \equiv CH \xrightarrow[\text{$HgSO_4$}]{\text{$H_2O, H_2SO_4$}} \stackrel{\hbox{Intermediate}}{\hbox{(A)}} \to \stackrel{\hbox{Product}}{\hbox{(B)}}$
answered
Mar 26, 2020
Ketones are formed on hydration of alkynes.https://clay6.com/mpaimg/1_c48.jpg
0
votes
Machanism of a hypothetical reaction $X_2 + Y_2 \to 2XY$ is given below.
(i) $X_2 \to X + X (fast)$
(ii) $X + Y_2 \rightleftharpoons XY + Y (slow)$
(iii) $X + Y \to XY (fast) $
The overall order of the reaction will be -
answered
Mar 26, 2020
solution :Correct the reactions given in Chemical Kinetics question as$X_2 \rightleftharpoons X+Y$(f...
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votes
Consider the reactions :
Identify A, X, Y and Z
answered
Mar 26, 2020
Solution :ince 'A' gives positive silver mirror test therefore, it must be an aldehyde or $\alpha$-h...
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A first order reaction has a specific reaction rate of $10^{–2} sec^{–1}$. How much time will it take for $20 \;g$ of the reactant to reduce to $5g$ ?
answered
Mar 26, 2020
Solution :$\large\frac{t_1}{2}=\frac{0.693}{k}=\frac{0.693}{0.01}$$=69.3\;sec$For first order reacti...
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