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Answers posted by meena.clay6
Questions
2990
answers
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0
votes
The structure of intermediate A in the following reaction is :-
answered
Apr 6, 2020
Solution :https://clay6.com/mpaimg/3_c19.jpg
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votes
The most suitable reagent for the following conversion is :-
answered
Apr 6, 2020
Solution :https://clay6.com/mpaimg/3_c18.jpg
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votes
The compound that is most difficult to protonate is:-
answered
Apr 6, 2020
Solution :Due to involvement of lone pair of electrons in resonance in phenol, it will have positive...
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votes
The method used to remove temporary hardness of water is :
answered
Apr 6, 2020
$Ca(HCO_3)_2+Ca(OH)_2 \to 2CaCO3 \downarrow +2H_2O$$Mg(HCO_3)_2+2Ca(OH)_2 \to 2CaCO_3 \downarrow +Mg...
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votes
What is the correct electronic configuration of the central atom in $K_4[Fe(CN)_6]$ based on crystal field theory?
answered
Apr 6, 2020
Solution :Clark's method is used to remove the temporary hardness of water, in which bicarbonates of...
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For the chemical reaction $N_2(g)+3H_2(g)\rightleftharpoons 2NH_3(g)$ the correct option is :
answered
Apr 6, 2020
Solution :$N_2+3H_2 \rightleftharpoons 2H_3$Rate of reaction is given as $\large\frac{d[N_2]}{dt}=\f...
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votes
Among the following, the reaction that proceeds through an electrophilic substitution is :
answered
Apr 6, 2020
Solution :https://clay6.com/mpaimg/3_c17.jpg
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A gas at 350 K and 15 bar has molar volume 20 percent smaller than that for an ideal gas under the same conditions. The correct option about the gas and its compressibility factor (Z) is :
answered
Apr 6, 2020
Solution :Compressibility factor (Z) $= V_{real}/V_{ideal}$$\therefore V_{real}/V_{ideal};Hence \;Z ...
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The non-essential amino acid among the following is :
answered
Apr 6, 2020
Solution :Amino acid, nonessential: An amino acid that can be made by humans and so is not essential...
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votes
Which of the following is incorrect statement ?
answered
Apr 6, 2020
Solution :$PbF_4$ and $SnF_4$ are ionic in nature.Hence option A is the correct answer.
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votes
In which case change in entropy is negative ?
answered
Apr 6, 2020
Solution :The change in entropy is negative when the disorder in an isolated system decreases and be...
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The mixture that forms maximum boiling azeotrope is :
answered
Apr 6, 2020
solution :Solutions showing negative deviation from Raoult's law form maximum boiling azeotrope.Wate...
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votes
Which of the following series of transitions in the spectrum of hydrogen atom falls in visible region ?
answered
Apr 6, 2020
Solution :1st four line of balmer series of spectrum of hydrogen atom falls in visible region.
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votes
Which one is malachite from the following ?
answered
Apr 6, 2020
Solution :Malachite is a copper carbonate hydroxide mineral, with the formula $Cu_2CO_3 (OH)_2$. Thi...
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Enzymes that utilize ATP in phosphate transfer require an alkaline earth metal (M) as the cofactor.M is :
answered
Apr 6, 2020
Solution :Enzymes that utilize ATP in phosphate transfer require magnesium (Mg) as the co-factor.
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An alkene "A" on reaction with $O_3$ and $Zn-H_2O$ gives propanone and ethanal in equimolar ratio.Addition of HCl to alkene "A" gives "B" as the major product. The structure of product "B" is :-
answered
Apr 6, 2020
Solution :https://clay6.com/mpaimg/3_c16.jpg
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votes
Which is the correct thermal stability order for$H_2E$ (E=O, S, Se, Te and Po) ?
answered
Apr 6, 2020
Solution :On going down the group thermal stability order for $H_2E$ decreases because H–E bond ener
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votes
The biodegradable polymer is :-
answered
Apr 6, 2020
Solution :A polymer that can be decomposed by bacteria is called a biodegradable polymerThe biodegra...
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votes
4d, 5d, 5f and 6p orbitals are arranged in the order of decreasing energy. The correct option is :-
answered
Apr 6, 2020
Solution :$(n+l) $ values for , $4d=4+2=6$$5p=5+1=6$$5f=5+3=8$$6p=6+1=7$$\therefore $ correct order ...
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Identify the incorrect statement related to $PCl_5$ from the following :-
answered
Apr 6, 2020
Solution :https://clay6.com/mpaimg/3_c15.jpgTrueAxial bond : 240 pm Equatorial bond :202 pmFalseDue ...
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votes
If the rate constant for a first order reaction is k,the time (t) required for the completion of 90% of the reaction is given by :-
answered
Apr 6, 2020
Solution :$k= \large\frac{2.303}{t}$$\log \large\frac{[A_0]}{[A]_t}$99 % completed reaction, $k =\la...
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votes
For the second period elements the correct increasing order of first ionisation enthalpy is :-
answered
Apr 6, 2020
Solution :Be’ and ‘N’ have comparatively more stable valence sub-shell than ‘B’ and ‘O’. Correct ord
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votes
The manganate and permanganate ions are tetrahedral, due to
answered
Apr 6, 2020
Solution :https://clay6.com/mpaimg/3_c14.jpg
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votes
Which of the following is an amphoteric hydroxide?
answered
Apr 6, 2020
Solution :$Be(OH)_2$ amphoteric in nature since it can react both with acid and base.$Be(OH)_ 2
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votes
Which of the following species is not stable ?
answered
Apr 6, 2020
Solution :Due to presence of d-orbital in Si, Ge and Sn they form species like $SiF_6^{2–}, [GeCl_6]
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votes
Which will make basic buffer ?
answered
Apr 6, 2020
https://clay6.com/mpaimg/3_c13.jpg
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votes
Conjugate base for Bronsted acids $H_2O$ and HF are:-
answered
Apr 6, 2020
Solution :https://clay6.com/mpaimg/3_c12.jpg
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votes
Which mixture of the solutions will lead to the formation of negatively charged colloidal $[AgI] I^{-}$ sol. ?
answered
Apr 6, 2020
solution :Generally charge present on the colloid is due to adsorption of common ion from dispersion...
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votes
The correct order of the basic strength of methyl substituted amines in aqueous solution is :-
answered
Apr 6, 2020
solution :$Kb$ of methyl substituted amines in auous solution depend upon combined effect of $+l$ o...
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votes
Among the following, the narrow spectrum antibiotic is
answered
Apr 6, 2020
Solution :Benzylpenicillin (Penicillin G) is narrow spectrum antibiotic used to treat infections cau...
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votes
Which of the following reactions are disproportionation reaction ? (a)$2Cu^{+} \to Cu^{2+}+Cu^0$ (b)$3MnO_4^{2-}+4H^{+} \to 2MnO_4^{-}+MnO_2$ (c)$2KMnO_4 \underrightarrow{\qquad \Delta \qquad } K_2MnO_4 +MnO_2 +O_2$ (d)$2MnO_4^{-}+3Mn^{2+}+2H_2O \longrightarrow 5MnO_2+4H^{\oplus}$ Select the correct option from the following
answered
Apr 6, 2020
Solution :https://clay6.com/mpaimg/3_c10.jpg
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votes
Which of the following diatomic molecular species has only $\pi$ bonds according to Molecular Orbital theory?
answered
Apr 6, 2020
Solution :MO configuration $C_2$ is :$\sigma 1s^2,\sigma 1s^2,\sigma 2s^2,\pi p_x^2=\pi 2 p^2_y$
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votes
The number of sigma $(\sigma)$ and pi $ (\pi)$ bonds in pent-2-en-4-yne is :-
answered
Apr 3, 2020
https://clay6.com/mpaimg/3_c8.jpgNumber of $\sigma$ bonds = 10and number of $\pi$ bonds = 3
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votes
Among the following, the one that is not a green house gas is :-
answered
Apr 3, 2020
Solution :A greenhouse gas is a gas that produces heat as it builds up in the atmosphere. It also b...
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votes
For a cell involving one electron$ E^\ominus$ cell = 0.59V at 298 K, the equilibrium constant for the cell reaction is :- $\bigg[Given \;that \frac{2.303RT}{F}=0.059V \;at \;T=298k\bigg]$
answered
Apr 3, 2020
Solution : Nearest equation$E_{cell}^{\theta} =E_{cell}^{\theta} -\large\frac{-0.059}{n}$$\log Q_c$A...
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votes
For an ideal solution, the correct option is :-
answered
Apr 3, 2020
Solution :For ideal solution :$\Delta _{mix}H=0$$\Delta_{mix} S>0$$\Delta _{mix} G=0$$\Delta _{mi...
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votes
The number of moles of hydrogen molecules required to produce 20 moles of ammonia through Haber's process is :-
answered
Apr 3, 2020
solution :Haber's process $N2(g) + 3H2(g) \rightleftharpoons 2NH_3(g)$ 20 moles need to be produced...
0
votes
pH of a saturated solution of $Ca(OH)_2$ is 9. The solubility product $(K_{sp}) $of $Ca(OH)_2$ is :-
answered
Apr 3, 2020
solution :$CO(OH)_2 \rightleftharpoons Ca^{2+}+2OH^{−}$$pH = 9$ Hence $pOH = 14 - 9 = 5$hence $[Ca^{
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votes
A compound is formed by cation C and anion A. The anions form hexagonal close packed (hcp) lattice and the cations occupy 75% of octahedral voids. The formula of the compound is :-
answered
Apr 3, 2020
Solution :Anions (A) are in hcp, so number of anions (A)=6Cations (C) are in 75%O.V., so number of c...
0
votes
Under isothermal condition, a gas at 300 K expands from 0.1L to 0.25L against a constant external pressure of 2 bar. The work done by the gas is :- [Given that 1L bar = 100 J]
answered
Apr 3, 2020
Solution :$W_{irr} = – P_{ext} \Delta V$$\qquad= – 2 bar \times (0.25 – 0.1)$$\qquad = – 2 \times 0
0
votes
Identify the major products P, Q and R in the following sequence of reactions :
answered
Apr 2, 2020
Solution :https://clay6.com/mpaimg/3_c7.jpg
0
votes
Which of the following compounds can form a zwitterion ?
answered
Apr 2, 2020
Solution :The molecule which forms zwitter ion is glycine.https://clay6.com/mpaimg/4_c6.jpg
0
votes
Given var der Waals constant for $NH_3, H_2, O_2$ and $CO_2$are respectively 4.17, 0.244, 1.36 and 3.59, which one of the following gases is most easily liquefied ?
answered
Apr 2, 2020
Solution :Critical temperature $\alpha$ van der waal constant (a) maximum ''a''⇒′′ gas with maximum
0
votes
The solubility of $BaSO_4$ in water is $2.42 \times 10^{-3} gL^{-1}$ at 298 K. The value of its solubility product $(K_{sp})$ will be
(Given molar mass of $BaSO_4 = 233 \; g\;mol^{-1}$ )
answered
Apr 2, 2020
Solution :Solubility of $BaSO_4=2.42 \times 10^{-3}gL^{-1}$$ \therefore S=(2.42 \times 10^{−5})2$$\q
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votes
On which of the following properties does the coagulating power of an ion depend ?
answered
Apr 2, 2020
Solution :The coagulating power of an ion depends on both magnitude and sign of the charge on the io...
0
votes
Following solutions were prepared by mixing different volumes of $NaOH$ and $HCl$ of different concentration :
pH of which one of them will be equal to 1 ?
answered
Apr 2, 2020
Solution :pH of 75 mL $\large\frac{ M}{5} HCl+25 mL \frac{ M}{5}$ NaOH will be equal to 1.T
0
votes
The type of isomerism shown by the complex $[CoCl_2(en)_2]$ is
answered
Apr 2, 2020
Solution :$[CoCl_2(en)_2]$, exhibit geometrical isomerism, as the coordination number of Co is 6 and...
0
votes
Which one of the following ions exhibits d-d transition and paramagnetism as well ?
answered
Apr 2, 2020
Solution :$MnO_4 => Mn^{+6} =[Ar]_3 d^1$$n=1$0 para magnetic and also shows d-d transition$d^0$ ...
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votes
The geometry and magnetic behaviour of the complex $[Ni(CO)_4]$ are
answered
Apr 2, 2020
The complexes having $sp_3$-hybridisation are tetrahedral while having $dsp2$ -hybridisation are squ...
0
votes
Iron carbonyl, $Fe(CO)_5$ is
answered
Apr 2, 2020
Solution :Iron carbonyl, $Fe(CO)_5 $is mononuclear. In $Fe(CO)_5$, one Fe atom is surrounded by 5 CO...
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