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Answers posted by mosymeow_1
Questions
352
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An inorganic salt when heated evolves a coloured gas which bleaches moist litmus paper. The evolved gas is
answered
Feb 1, 2014
Answer: $Cl_2$ $Cl_2$ is a greenish yellow gas which bleaches litmus paper by oxidation$Cl_2 +...
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Heating of oxalic acid with conc. $H_2SO_4$ gives
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Feb 1, 2014
Answer: $CO + CO_2$ When oxalic acid is heated in the presence of concentrated sulphuric acid, oxali...
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A test tube containing a nitrate and another containing a bromide and $MnO_2$ are treated with conc. $H_2SO_4$. The brown fumes evolved are passed through water. The water will be coloured by
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Feb 1, 2014
Answer: the bromide $NO^-_3$ gives $NO_3$ with conc. $H_2SO_4$ which on pasing through water ...
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When a salt is heated with dil $H_2SO_4$ and $KMnO_4$ solution, the pink colour of $KMnO_4$ is discharged, the mixture contains:
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Feb 1, 2014
Answer: Sulphite $SO_3^{2-}$ reduces $KMnO_4$ and colour of $KMnO_4$ is discharged.$5SO_3^{2-...
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When borax is heated in a platinum loop, the transparent bead formed contains
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Feb 1, 2014
Answer: Sodium metaborate + $B_2O_3$ $Na_2B_4O_7.10H_2O$ (Borax) $\xrightarrow[Pt. loop]{\Del...
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The most suitable indicator for the titrations of $Ba(OH)_2$ against HI is
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Feb 1, 2014
Toolbox:Suitable indicator for strong acid-strong base titrations are phenolphthalein & methyl o...
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If $pK_{in}$ of an indicator is 10.5, the pH transition range for which it is most suitable is
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Feb 1, 2014
Answer: 9.5-11.5 The pH transition range for an indicator = $pK_{in}\pm 1 = 10.5 \pm 1$Theref...
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The most suitable indicator for the titration of HCOOH against NaOH is
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Feb 1, 2014
Toolbox:Indicator for strong acid-strong base titrations: phenolphthalein, methyl orangeIndicator fo...
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Completion of diazotisation can be checked with
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Feb 1, 2014
Answer: Starch KI paper Completion of diazotisation can be checked with starch KI paper. Exce...
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$C_6H_5OH$ and $C_2H_5OH$ can be distinguished by
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Feb 1, 2014
Answer: Litmus test $C_6H_5OH$ (phenol) and $C_2H_5OH$ (ethanol) can be distinguished by litm...
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Which of the following compound will give blood red colour while doing the Lassigne's test for N?
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Feb 1, 2014
Answer: $H_2N(C_6H_4)SO_3H$ $H_2N(C_6H_4)SO_3H$ contains N, S and C. During fusion with sodium...
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Presence of nitrogen in which of the following compound cannot be detected by Lassaigne's test?
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Jan 30, 2014
Answer: HydrazineAs no carbon is present in hydrazine, no NaCN is formed during sodium fusion test.
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Flame test is not given by
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Jan 28, 2014
Answer: $Be^{2+}$ ions $Be^{2+}$ ions does not give flame test because of its high ionisation e...
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$[X] + H_2SO_4 \longrightarrow [Y]$ colourless with irritating smell. $[Y] + K_2Cr_2O_7 + H_2SO_4 \longrightarrow$ Green solution. [X] and [Y] are
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Jan 28, 2014
Answer: $SO_3^{2-}, SO_2$ $[X]=SO_3^{2-}$ ion, $[Y]=SO_2$$SO_3^{2-} + H_2SO_4 \longrightarrow S...
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The ion that cannot be precipitated by both $HCl$ and $H_2S$
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Jan 28, 2014
Answer: $Sn^{2+}$ $Pb^{2+}$ and $Ag^+$ can be precipitated both by $HCl$ and $H_2S$. $Cu^{2+}$ ...
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Potassium cyanide is used for separating
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Jan 28, 2014
Answer: $Co^{2+}$ and $Ni^{2+}$ When heated with KCN solution $Ni^{2+}$ forms potassium nickelc...
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How do we differentiate between $Fe^{3+}$ and $Cr^{3+}$ in groupIII?
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Jan 28, 2014
Toolbox:$OH^-$ ions precipitate both $Fe^{3+}$ and $Cr^{3+}$ as their hydroxides. However, $Cr(OH)_3...
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When a substance 'A' reacts with water, it produces a combustible gas 'B' and a solution of substance 'C' in water. When another substance 'D' reacts with this solution of 'C', it also produces the same gas 'B' on warming but 'D' can produce gas 'B' on reaction with dilute sulphuric acid at room temperature. 'A' imparts a deep golden yelow colour to the smokeless flame of bunsen flame. 'A', 'B' , 'C' & 'D' are respectively
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Jan 28, 2014
Answer: $Na, H_2, NaOH, Zn$ When Na reacts with water, it produces a ...
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Three separate samples of a solution of a single salt gave these results. One formed a white ppt. with excess ammonia solution, one formed a white ppt. with dil. NaCl solution and one formed a black ppt. with $H_2S$. The salt could be:
answered
Jan 28, 2014
Answer: $Pb(NO_3)_2$ $Pb(NO_3)_2 + 2NH_4OH \longrightarrow Pb(OH)_2 \downarrow (\text{white pp...
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The only cations present in a slightly acidic solution are $Fe^{3+}, Zn^{2+}$ and $Cu^{2+}$. The reagent that when added in excess to this solution would identify and separate $Fe^{3+}$ in one step is
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Jan 28, 2014
Answer: 6M $NH_3$$Fe^{3+} + Zn^{2+} + Cu^{2+} \xrightarrow{\text{6M } NH_3} Fe(OH)_3 \text{(brown pp...
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When $K_2Cr_2O_7$ crystals are heated with conc. HCl, the gas evolved is
answered
Jan 28, 2014
Answer: $Cl_2$ $K_2Cr_2O_7 + 8HCl \longrightarrow 2KCl + 2CrCl_3 + 4H_2O + 3[O]${$2HCl + [O] \l...
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A pale green crystalline metal salt $M$ dissolves freely in water. It gives a brown precipitate on addition of aqueous $NaOH$. The metal salt solution also gives a black precipitate on bubbling $H_2S$ in aqueous medium. An aqueous solution of the metal salt decolourises the pink colour of the permanganate solution. The metal in the metal salt solution is
answered
Jan 28, 2014
Answer: Iron Pale green salt contains a mixture of $Fe^{2+}$ and $Fe^{3+}$ ions$Fe^{3+} + 3OH^- \lon...
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Which of the following salt would give $SO_2$ with hot and dil. $H_2SO_4$ and also decolourise $Br_2$ water?
answered
Jan 28, 2014
Answer: $Na_2SO_3$$Na_2SO_3 + H_2SO_4 \longrightarrow Na_2SO_4 + SO_2 \uparrow + H_2O$Sodium sulphat...
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An aqueous solution of coloureless metal sulphate M gives a white precipitate with $NH_4OH$. This was soluble in excess of $NH_4OH$. On passing $H_2S$ through this solution a white ppt is formed. The metal M in the salt is
answered
Jan 28, 2014
Answer: Zn$Zn^{2+} + 2NH_4OH \longrightarrow Zn(OH)_2$ (White ppt.)$ + 2NH_4^+$$Zn(OH)_2 + 2NH_4OH \...
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A metal salt solution forms a yellow precipitate with potassium chromate in acetic acid, a white precipitate with dilute $H_2SO_4$ but gives no precipitate with sodium chloride or iodide, it is
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Jan 28, 2014
Answer: Barium carbonate $BaCO_3 + 2CH_3COOH \longrightarrow Ba(CH_3COO)_2 + CO_2 + H_2O$$Ba(CH_3COO...
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$K_4[Fe(CN)_6]$ can be used to detect one or more out of $Fe^{2+}, Fe^{3+}, Zn^{2+}, Cu^{2+}, Cd^{2+}$
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Jan 28, 2014
Answer: All but $Fe^{2+}$ $2ZnCl_2 + K_4[Fe(CN)_6] \xrightarrow{CH_3COOH} Zn_2[Fe(CN)_6]_3 ...
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$NH_4CNS$ can be used to test one or more out of $Fe^{3+}, Co^{2+}, Cu^{2+}$
answered
Jan 28, 2014
Answer: all$CoCl_2 + 4NH_4CNS \overset{ether}{\longrightarrow} (NH_4)_2[Co(CNS)_4] \text{(Blue colou...
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Potassium ferrocyanide is used in the detection of
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Jan 28, 2014
Answer: Both $Cu^{2+}$ & $Fe^{3+}$ ions Both $Cu^{2+}$ & $Fe^{3+}$ ions can be detected...
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In the fourth group, $Mn(OH)_2$ on heating with $PbO_2$ and conc. $HNO_3$ gives pink colour due to the formation of
answered
Jan 28, 2014
Answer: $KMnO_4$ $Mn(OH)_2 + 2HNO_3 \longrightarrow Mn(NO_3)_2 + 2H_2O$ On heating,$2Mn(NO_3)_...
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To aviod the precipitation of hydroxide of $Ni^{2+}, Co^{2+}, Mn^{2+}$ along with those of the third group cations, the solutions should be
answered
Jan 28, 2014
Answer: Heated with excess of ammonium chloride Function of strong electrolyte $NH_4Cl$ is to ...
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Mark the compound which turns black with $NH_4OH$
answered
Jan 28, 2014
Answer: Mercurous Chloride $Hg_2Cl_2 + 2NH_4OH \longrightarrow [NH_2-Hg-Hg-Cl]$ (unstable comp...
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Chromyl chloride vapours are dissolved in water and acetic acid and lead acetate solution is added, then
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Jan 28, 2014
Answer: A yellow ppt. will be obtained $CrO_2Cl_2 + 2H_2O \longrightarrow H_2CrO_4 + 2HCl$Chr...
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In a combination of $NO_3^-, Br^-$ and $I^-$ present in a mixture, $Br^-$ and $I^-$ interfere in the ring test for $NO_3^-$. These are removed by adding a solution of
answered
Jan 28, 2014
Answer: $Ag_2SO_4$ $2Br^- + Ag_2SO_4 \longrightarrow 2AgBr \downarrow + SO_4^{2-}$$2I^- + Ag_2S...
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$BaCl_2$ solution gives a white ppt. with a solution of a salt, which dissolves in dil. HCl with the evolution of a colourless, pungent smelling gas. The acid radical in the salt is
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Jan 28, 2014
Answer: $SO_3^{2-}$ $SO_3^{2-} + Ba^{2+} \longrightarrow BaSO_3 \downarrow$ (White ppt.)$BaSO_...
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To a solution of a salt, $MgSO_4$ solution is added and white ppt. appears only on heating. The acid radical in the salt is
answered
Jan 28, 2014
Answer: $HCO_3^-$ $2NaHCO_3 + MgSO_4 \longrightarrow Mg(HCO_3)_2 + H_2O + CO_2$saltOn heating,...
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On heating a mixture of potassium dichromate and sodium chloride with concentrated sulphuric acid in a dry test tube, the compound formed
answered
Jan 28, 2014
Answer: Chromyl chloride $4NaCl(s) + K_2Cr_2O_7(s) + 3H_2SO_4(l) \overset{\Delta}{\longrightarr...
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Nitrate is confirmed by ring test. The brown colour of the ring test is due to the formation of
answered
Jan 28, 2014
Answer: $FeSO_4.NO$ $NaNO_3 + H_2SO_4 \longrightarrow NaHSO_4 + HNO_3$Now, $4FeSO_4 \text{(Ferr...
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Production of a green edged flame on igniting the vapours evolved by heating a given inorganic salt with few mL of ethyl alcohol and conc. $H_2SO_4$ indicates the presence of a
answered
Jan 26, 2014
Toolbox:Ethyl Borate is Volatile and burns with a green edged flame.Answer: Borate $NaBO_3 + 2...
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NaCl , NaBr and NaI mixture on heating with conc. $H_2SO_4$ gives gases respectively
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Jan 26, 2014
Answer: $HCl, Br_2, I_2$$NaCl + H_2SO_4 \overset{\Delta}{\longrightarrow} NaHSO_4 + HCl \uparrow $$H...
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A salt on reaction with dil. $H_2SO_4$ gives a reddish brown gas. The salt is
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Jan 26, 2014
Answer: $KNO_2$ $2KNO_2 + H_2SO_4 \longrightarrow K_2SO_4 + HNO_2$$3HNO_2 \longrightarrow HNO_3...
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A few drops of conc $H_2SO_4$ is added to the solution of $FeSO_4$ in water to
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Jan 26, 2014
Answer: prevent salt hydrolysisA few drops of conc. $H_SO_4$ added to a solution of $FeSO_4$ [or $Al...
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Which of the following test can be used to distinguish between phenol and cyclohexanol?
answered
Jan 26, 2014
Answer: $Br_2$ water test phenol ...
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In Lassaigne's test when both N and S are present, blood red colour is due to the formation of
answered
Jan 26, 2014
Nitrogen, Sulphur and halogens, if present in an organic compound are detected by Lassaigne's test...
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On heating ammonium dichromate the gas evolved is
answered
Jan 26, 2014
Answer: Nitrogen $(NH_4)_2Cr_2O_7 \overset{\Delta} {\longrightarrow} Cr_2O_3 + 4H_2O + ...
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Which one among the following pairs of ions cannot be separated by $H_2S$ in dilute hydrochloric acid?
answered
Jan 26, 2014
Answer: $Bi^{3-}, Sn^{4+}$ $Bi^{3-}$ and $Sn^{4+}$ belong to III group and thus cannot ...
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votes
The phenomenon in which white transparent crystal changes into white powder is called
answered
Jan 26, 2014
Toolbox: In chemistry, efflorescence is the loss of water (or a solvent) of crystallizati...
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votes
Which of the following is not precipitated as sulphide by passing $H_2S$ in the presence of conc. HCl?
answered
Jan 26, 2014
Answer: Cadmium Solubility product of CdS is greater than the other sulphides of group II, it is...
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votes
A one litre flask is full of brown bromine fumes. The intensity of brown colour of vapour will not decrease appreciably on adding to the flask some
answered
Jan 26, 2014
Marble $(CaCO_3)$ does not react, adsorb, adsorb or dissolve $Br_2$. So the intensity of brown colou...
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votes
A mixture of two salts is not water soluble but dissolves completely in dil. HCl to form a colourless solution. The mixture could be
answered
Jan 26, 2014
Answer: $BaCO_3$ and $ZnS$ $BaCO_3$ + $ZnS$ mixture dissolves in HCl but is insoluble in water. ...
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Which of the following is soluble in yellow ammonium sulphide?
answered
Jan 26, 2014
Answer: SnS $SnS + (NH_4)_2S +S \longrightarrow (NH_4)_2SnS_3$ $(NH_4)_2S$ is yellow ammonium ...
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